“关-开”型半花菁类荧光探针对黑茶抗氧化活性的测定
作者：
许超;汪楠;夏婷;罗苗;曹一鸣;...
期刊：
湖南城市学院学报(自然科学版) ,2019年28(03):69-73 ISSN：1672-7304
作者机构：
湖南城市学院 材料与化学工程学院,黑茶金花湖南省重点实验室,湖南 益阳 413000;湖南大学 化学生物传感与计量学国家重点实验室,长沙 410082;[刘长辉; 罗苗; 齐风佩; 龙立平; 曹一鸣; 夏婷; 许超; 汪楠] 湖南城市学院
关键词：
黑茶;抗氧化活性;铁离子;荧光分析
摘要：
以N-乙基苯并吲哚与对苯二甲醛缩合产物为底物,其缩合后产物(EFDB)与2,3-二氨基丁烯二腈缩合得新型的半花菁类衍生物(EADB),采用1H NMR及质谱进行结构表征.铁离子诱导EADB荧光信号明显增强,且体系荧光信号的变化与铁离子浓度在2～100 mol/L范围内呈良好的线性关系,检出限为0.54 mol/L.采用铁离子介导的"关-开"策略,构建了黑茶抗氧化活性的测定方法,并成功应用于实际样品.
语种：
中文
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“关-开”型近红外荧光探针用于铁离子和黑茶抗氧化活性测定
作者：
Wang Zhen-Rui;Qi Feng-Pei* ;Luo Miao;Cao Yi-Ming;Liu Hong-Tao;...
期刊：
分析化学 ,2019年47(1):112-118 ISSN：0253-3820
通讯作者：
Qi Feng-Pei;Liu Chang-Hui
作者机构：
[Qi Feng-Pei; Liu Chang-Hui; Su Jian-Ke; Long Li-Ping; Cao Yi-Ming; Luo Miao; Zhang Chang-Qing; Wang Zhen-Rui; Liu Hong-Tao; Qi, FP; Liu, CH] Hunan City Univ, Coll Mat & Chem Engn, Hunan Prov Key Lab Dark Tea & Jin Hua, Yiyang 413000, Peoples R China.;[Liu Chang-Hui] Hunan Univ, State Key Lab Chemobiosensing & Chemometr, Changsha 410082, Hunan, Peoples R China.
通讯机构：
[Qi, FP; Liu, CH; Liu Chang-Hui] H;Hunan City Univ, Coll Mat & Chem Engn, Hunan Prov Key Lab Dark Tea & Jin Hua, Yiyang 413000, Peoples R China.;Hunan Univ, State Key Lab Chemobiosensing & Chemometr, Changsha 410082, Hunan, Peoples R China.
关键词：
铁离子;半胱氨酸;近红外探针;黑茶;抗氧化活性
摘要：
以4-甲基喹啉与二醛缩合剂反应得到新型喹啉基花菁类衍生物CyQ,用~1H NMR、HRMS-ESI确证其结构。CyQ与半胱氨酸(Cys)通过卤素-巯基亲核取代和重排反应得到CyQ-Cys,而铁离子(Fe~(3+))可诱导CyQCys荧光信号明显增强,且荧光信号的变化与Fe~(3+)浓度在40 ~ 300 μmol/L范围内呈现良好的线性关系,线性回归方程为y = 1.0619x+0.01355 (R~2= 0.9910),检出限为10.4 μmol/L(S/N= 3) 。同时,利用黑茶金花可还原Fe~(3+)的性质,采用Fe~(3+)介导的“关-开”策略,建立了黑茶抗氧化活性的荧光分析方法。
语种：
中文
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A nucleic acid cleavage-based fluorescent probe for the detection of copper ions in pure aqueous solution
作者：
Deng, Qirong;Wang, Nan;Su, Jianke;Liu, Aijuan;Zhang, Jin;...
期刊：
ANALYTICAL METHODS ,2019年11(20):2630-2633 ISSN：1759-9660
通讯作者：
Tang, Ruiren;Qi, Fengpei;Liu, Changhui
作者机构：
[Tang, Ruiren; Deng, Qirong] Cent S Univ, Sch Chem & Chem Engn, Changsha 410083, Hunan, Peoples R China.;[Qi, Fengpei; Su, Jianke; Zhang, Jin; Liu, Changhui; Wang, Nan; Long, Liping; Qi, FP; Liu, CH] Hunan City Univ, Coll Mat & Chem Engn, Hunan Prov Key Lab Dark Tea & Jin Hua, Yiyang 413000, Peoples R China.;[Liu, Aijuan] Beijing Univ Chinese Med, Sch Humanities, Beijing 100029, Peoples R China.;[Liu, Changhui] Hunan Univ, State Key Lab Chemo Biosensing & Chemometr, Changsha 410082, Hunan, Peoples R China.
通讯机构：
[Tang, Ruiren] C;[Qi, FP; Liu, CH; Liu, Changhui] H;Cent S Univ, Sch Chem & Chem Engn, Changsha 410083, Hunan, Peoples R China.;Hunan City Univ, Coll Mat & Chem Engn, Hunan Prov Key Lab Dark Tea & Jin Hua, Yiyang 413000, Peoples R China.;Hunan Univ, State Key Lab Chemo Biosensing & Chemometr, Changsha 410082, Hunan, Peoples R China.
摘要：
Herein, a novel carbazole derivative of BEVC was designed with an enhanced fluorescence signal by a G-quadruplex, and thus a fluorescent probe of G-quadruplex/BEVC was obtained by aggregation-induced emission, which could exhibit a decreased fluorescence signal in the presence of Cu2+via the Fenton reaction, demonstrating great potential for Cu2+ assay in pure aqueous solution. © 2019 The Royal Society of Chemistry.
语种：
英文
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Reversible Fluorescent Turn-on Sensors for Fe3+ based on a Receptor Composed of Tri-oxygen Atoms of Amide Groups in Water
作者：
Wang, Jiaoliang;Long, Liping* ;Xiao, Guing;Fang, Fang
期刊：
Open Chemistry ,2018年16(1):1268-1274 ISSN：2391-5420
通讯作者：
Long, Liping
作者机构：
[Wang, Jiaoliang; Fang, Fang; Xiao, Guing; Long, Liping] Hunan City Univ, Coll Mat & Chem Engn, Hunan Prov Key Lab Dark Tea & Jin Hua, Yiyang 413000, Hunan, Peoples R China.
通讯机构：
[Long, Liping] H;Hunan City Univ, Coll Mat & Chem Engn, Hunan Prov Key Lab Dark Tea & Jin Hua, Yiyang 413000, Hunan, Peoples R China.
关键词：
Sensor;Reversibility;Fe3+;tri-oxygen
摘要：
<jats:title>Abstract</jats:title><jats:p>Compounds <jats:bold>Rh6G-1</jats:bold> and <jats:bold>RhB-2</jats:bold> with a novel receptor composed of tri-oxygen atoms of amide groups were designed and synthesized as new reversible fluorescent sensors for Fe<jats:sup>3+</jats:sup>. The prominent features of the novel sensor <jats:bold>Rh6G-1</jats:bold> include a large fluorescence turn-on response in essentially pure water at room temperature, high sensitivity, high selectivity, a limit of detection, cell membrane permeability, and low cytotoxicity. These desirable attributes enable us to successfully employ the new sensor <jats:bold>Rh6G-1</jats:bold> for Fe<jats:sup>3+</jats:sup> bioimaging in living cells.</jats:p>
语种：
英文
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Fluorescence detection of glutathione and oxidized glutathione in blood with a NIR-excitable cyanine probe
作者：
Liu, Chang-hui* ;Qi, Feng-pei;Wen, Fu-bin;Long, Li-ping;Liu, Ai-juan;...
期刊：
Methods and Applications in Fluorescence ,2018年6(2):024001 ISSN：2050-6120
通讯作者：
Liu, Chang-hui;Yang, Rong-hua
作者机构：
[Liu, CH; Yang, Rong-hua; Liu, Chang-hui] Changsha Univ Sci & Technol, Sch Chem & Biol Engn, Changsha 410004, Hunan, Peoples R China.;[Liu, Chang-hui; Wen, Fu-bin; Qi, Feng-pei; Long, Li-ping] Hunan City Univ, Coll Mat & Chem Engn, Yiyang 413000, Peoples R China.;[Liu, CH; Yang, Rong-hua; Liu, Chang-hui] Beijing Univ Chinese Med, Sch Humanities, Beijing 100029, Peoples R China.
通讯机构：
[Liu, CH; Yang, RH] C;[Liu, Chang-hui] H;[Liu, CH; Yang, RH] B;Changsha Univ Sci & Technol, Sch Chem & Biol Engn, Changsha 410004, Hunan, Peoples R China.;Hunan City Univ, Coll Mat & Chem Engn, Yiyang 413000, Peoples R China.
关键词：
carbocyanine;fluorescent dye;glutathione;nicotinamide adenine dinucleotide phosphate;blood;chemistry;human;near infrared spectroscopy;oxidation reduction reaction;Carbocyanines;Fluorescent Dyes;Glutathione;Humans;NADP;Oxidation-Reduction;Spectroscopy, Near-Infrared
摘要：
Cyanine has been widely utilized as a near infrared (NIR) fluorophore for detection of glutathione (GSH). However, the excitation of most of the reported cyanine-based probes was less than 800 nm, which inevitably induce biological background absorption and lower the sensitivity, limiting their use for detection of GSH in blood samples. To address this issue, here, a heptamethine cyanine probe (DNIR), with a NIR excitation wavelength at 804 nm and a NIR emission wavelength at 832 nm, is employed for the detection of GSH and its oxidized form (GSSG) in blood. The probe displays excellent selectivity for GSH over GSSG and other amino acids, and rapid response to GSH, in particular a good property for indirect detection of GSSG in the presence of enzyme glutathione reductase and the reducing agent nicotinamideadenine dinucleotide phosphate, without further separation prior to fluorescent measurement. To the best of our knowledge, this is the first attempt to explore NIR fluorescent approach for the simultaneous assay of GSH and GSSG in blood. As such, we expect that our fluorescence sensors with both NIR excitation and NIR emission make this strategy suitable for the application in complex physiological systems. © 2018 IOP Publishing Ltd.
语种：
英文
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化工原理实验中双纵坐标图的绘制方法
作者：
尹志芳;王锋;曾永林;胡拥军;龙立平
期刊：
教育教学论坛 ,2018年(21):185-186 ISSN：1674-9324
作者机构：
湖南城市学院材料与化学工程学院,湖南 益阳,413000;[龙立平; 曾永林; 尹志芳; 王锋; 胡拥军] 湖南城市学院
关键词：
化工原理实验;双纵坐标
摘要：
化工原理实验数据处理过程中经常会碰到双纵坐标图的绘制,文章以Excel和Sigmaplot工具为例,针对离心泵特性曲线的测定实验数据,分别介绍了双纵坐标图的绘制方法。学生通过对绘图工具进行多方面、多层次的深入学习,进一步加深对实验数据的分析能力,提高数据处理技能。
语种：
中文
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基于石墨烯分子印迹电化学传感器测定芦丁
作者：
谢丹;龙立平;刘蓉;钟桐生;李媛;...
期刊：
分析科学学报 ,2017年33(4):545-548 ISSN：1006-6144
作者机构：
[谢丹; 龙立平; 刘蓉; 钟桐生; 李媛; 唐桥亭] 湖南城市学院材料与化学工程学院, 湖南, 益阳, 413000
关键词：
分子印迹传感器;循环伏安法;石墨烯;芦丁
摘要：
将石墨烯(GR)滴涂至裸Au电极表面,并以邻氨基酚为功能单体,芦丁为模板分子,制备了芦丁分子印迹膜电化学传感器,利用循环伏安法(CV)和差分脉冲伏安法(DPV)对制得的传感器进行了电化学性能研究,并且对制备条件和测定条件进行了优化。结果表明,与裸Au电极相比,该GR修饰的Au电极在[Fe(CN)_6]~(3-)/~(4-)溶液中峰电流明显增大,显著提高了芦丁分子印迹传感器的灵敏度。在最优实验条件下,基于 GR分子印迹电化学传感器在4. 40×10~(-6)~2. 80×10~(-4) mol/L范围内呈良好的线性关系,检测限为1.46×10~(-6) mol/L。用该传感器测定了黑茶中芦丁的含量,获得较好结果。
语种：
中文
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A NIR fluorescent probe for the rapid detection of Hg2+ in living cells and in vivo mice imaging
作者：
Wang, Jiaoliang;Long, Liping* ;Xia, Li;Fang, Fang
期刊：
Methods and Applications in Fluorescence ,2017年5(2):025002 ISSN：2050-6120
通讯作者：
Long, Liping
作者机构：
[Wang, Jiaoliang; Fang, Fang; Long, Liping; Xia, Li] Hunan City Univ, Coll Chem & Environm Engn, Yiyang 413000, Hunan, Peoples R China.
通讯机构：
[Long, Liping] H;Hunan City Univ, Coll Chem & Environm Engn, Yiyang 413000, Hunan, Peoples R China.
关键词：
fluorescent dye;mercury;oxazole derivative;spironolactone;animal;chemistry;fluorescence microscopy;HeLa cell line;human;mouse;spectrofluorometry;Animals;Fluorescent Dyes;HeLa Cells;Humans;Mercury;Mice;Microscopy, Fluorescence;Oxazoles;Spectrometry, Fluorescence;Spironolactone
摘要：
A near-infrared fluorescent probe NIR-Hg, for the detection of Hg2+ ion, has been synthesized directly by condensing Changsha dye with 4-Phenyl-3-thiosemicarbazide and the structure has fully characterized by 1HNMR, 13CNMR, and ESI-MS. The probe has been designed on the basis of the reaction that Hg2+ ion promotes thiosemicarbazide to oxazole in aqueous media and had been induced to produce turn-on fluorescence via an irreversible spirolactam ring-opening process. The probe NIR-Hg has exhibited fast response (1 min), high sensitivity with 44-fold fluorescence intensity enhancement under six equivalent amounts of Hg2+ added, high selectivity over other related metal ions and a low detection limit of 5.8 × 10-8 M in the phosphate buffer. The linear response range covers the concentration of Hg2+ from 5 × 10-7 to 5 × 10-6 M. In addition, the probe has good cell-membrane permeability, which is suitable for fluorescence imaging for Hg2+ in living cells and in vivo mice. © 2017 IOP Publishing Ltd.
语种：
英文
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“翻转课堂”在化工原理实验教学中的实施策略
作者：
尹志芳;胡拥军;王锋;曾永林;龙立平
期刊：
广州化工 ,2017年45(14):190-192 ISSN：1001-9677
作者机构：
湖南城市学院材料与化学工程学院,湖南 益阳,413000;[龙立平; 曾永林; 尹志芳; 王锋; 胡拥军] 湖南城市学院
关键词：
翻转课堂;化工原理实验;实施策略
摘要：
结合化工原理实验教学内容的特点,设计了分层次"翻转课堂"具体教学模式、 实施方案和考核指标,重点培养学生的创造性和发散性思维,对其原有的认知结构不断地进行反思和重构,形成新的认知结构.结果表明:经过化工原理实验"翻转课堂"的教学实践,学生综合能力普遍得到加强,在每学期末,在每个任课班随机抽查5名同学,现场随机指定一个实验项目,80%的学生能较熟练的独立完成实验,达到了预期目的.
语种：
中文
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转型地方本科院校学生工程实践能力培养
作者：
刘长辉;王锋;林立;胡拥军;龙立平
期刊：
广东化工 ,2017年44(16):281-282 ISSN：1007-1865
作者机构：
湖南城市学院材料与化学工程学院,湖南益阳,413000;[刘长辉; 龙立平; 王锋; 林立; 胡拥军] 湖南城市学院
关键词：
工程实践能力;转型;地方本科院校;培养
摘要：
在地方本科院校向应用型转型发展的背景下,应用型本科院校人才培养质量的核心是工程实践能力。分析转型中的地方本科院校学生工程实践能力提升不明显的成因,并从评价体系、师资队伍建设、实践课程建设及管理体制和激励机制等主要方面探索应用型本科院校学生工程实践能力培养的措施,以提升学生的工程实践能力和应用型人才培养质量。
语种：
中文
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Development of a near-infrared fluorescence turn-on probe for imaging Hg2+ in living cells and animals
作者：
Wang, Jiaoliang;Li, Weiling;Long, Liping*
期刊：
Sensors and Actuators B-Chemical ,2017年245:462-469 ISSN：0925-4005
通讯作者：
Long, Liping
作者机构：
[Wang, Jiaoliang; Long, Liping] Hunan City Univ, Coll Chem & Environm Engn, Yiyang 413000, Hunan, Peoples R China.;[Li, Weiling] Hunan Univ, Coll Chem & Chem Engn, State Key Lab Chemo Biosensing & Chemometr, Changsha 410082, Hunan, Peoples R China.
通讯机构：
[Long, Liping] H;Hunan City Univ, Coll Chem & Environm Engn, Yiyang 413000, Hunan, Peoples R China.
关键词：
CS dye;Mercury ion;NIR fluorescent probe;Vivo imaging
摘要：
Mercury is one of the deadly toxic metals to humans. A new fluorescent probe CS-Hg for Hg<sup>2+</sup>has been designed and synthesized based on the Hg<sup>2+</sup>-promoted cyclization and the CS NIR platform. The probe upon interaction with different metal ions showed good sensitivity and high selectivity for Hg<sup>2+</sup>through fluorescence “turn-on”response in PBS buffer. Significantly, the probe CS-Hg is highly reactive to Hg<sup>2+</sup>with a very rapid response. Furthermore, we have demonstrated that the probe is applicable for Hg<sup>2+</sup>imaging in the living cells and in animals. ©2017 Elsevier B.V.
语种：
英文
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掺杂羟基磷灰石和石墨烯的碳糊电极测铅和镉
作者：
刘蓉;龙立平;胡拥军;呼晓增
作者机构：
湖南城市学院化学与环境工学院,湖南益阳,413000
会议名称：
第十二届全国电分析化学学术会议
会议时间：
201404
会议地点：
桂林
会议论文集名称：
第十二届全国电分析化学学术会议论文集
关键词：
水质监测;铅元素;镉元素;碳糊电极;羟基磷灰石;石墨烯
摘要：
本文主要研究掺杂羟基磷灰石和石墨烯碳糊电极在差分脉冲伏安法(DPV)的条件下同时测定Pb2+和Cd2+,对实验参数:掺杂羟基磷灰石和石墨烯的比例、盐酸的浓度、沉积时间和沉积电位进行了优化.最优的实验条件为:羟基磷灰石和石墨烯比例分别为20％和2％,盐酸浓度0.24mol/L,沉积时间50s,沉积电位-1.3V.在最优实验条件下用DPV法对不同浓度的Pb2+和Cd2+进行了同时测定,Pb2+和Cd2+的线性方程分别为IPb2+(A)=-0.06306-0.05539 C(mol/L)(R=-0.9920);ICd2+(A)=-0.1100-0.01514C(mol/L)(R=-0.9996),富集时间为150s,Pb2+、Cd2+的检出限分别为:2.20110-7mol/L;1.35210-6mol/L,回收率分别为:105.6％和103.3％.
语种：
中文
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A fast-responsive fluorescent probe for sulfite and its bioimaging
作者：
Wang, Jiaoliang* ;Long, Liping;Xiao, Xiaoming
期刊：
LUMINESCENCE ,2016年31(3):775-781 ISSN：1522-7235
通讯作者：
Wang, Jiaoliang
作者机构：
[Wang, Jiaoliang] Univ South China, Coll Chem & Chem Engn, Hengyang, Hunan, Peoples R China.;[Wang, Jiaoliang; Long, Liping] Hunan City Univ, Coll Chem & Environm Engn, Yiyang, Hunan, Peoples R China.;[Wang, Jiaoliang] Hunan Univ, State Key Lab Chemobiosensing & Chemometr, Changsha 410082, Hunan, Peoples R China.;[Xiao, Xiaoming] Hunan Normal Univ, Key Lab Chem Biol & Tradit Chinese Med Res, Minist Educ, Changsha, Hunan, Peoples R China.
通讯机构：
[Wang, Jiaoliang] U;Univ South China, Coll Chem & Chem Engn, Hengyang, Hunan, Peoples R China.
关键词：
Fluorescence;Fluorescence spectroscopy;Probes;Aqueous media;Bio-imaging;Cell imaging;Fast response;Fast responsive;Fluorescent probes;Living cell imaging;Nucleophilic additions;Rapid detection;Water solubilities;Addition reactions;coumarin;coumarin derivative;fluorescent dye;sulfite;sulfur dioxide;chemical structure;chemistry;fluorescence;HeLa cell line;human;solubility;spectrofluorometry;synthesis;time factor;tumor cell culture;Coumarins;Fluorescence;Fluorescent Dyes;HeLa Cells;Humans;Molecular Structure;Solubility;Spectrometry, Fluorescence;Sulfites;Sulfur Dioxide;Time Factors;Tumor Cells, Cultured
摘要：
A turn-on fluorescent probe Coumarin-SO2 based on a nucleophilic addition reaction was developed for the rapid detection of SO32- in aqueous media. The probe Coumarin-SO2 displays excellent water solubility, fast response, highly sensitivity and highly selectivity over other biological related species. More importantly, living cell imaging experiments indicate the feasibility of using the probe for the detection of SO32- in biological systems. Copyright © 2015 John Wiley & Sons, Ltd.
语种：
英文
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桑色素分子印迹传感器的制备与应用
作者：
Liu Rong;Long Li-Ping* ;Lei Cun-Xi;Wu Zhao-Yang;Liu Yu;...
期刊：
分析化学 ,2016年44(3):385-390 ISSN：0253-3820
通讯作者：
Long Li-Ping
作者机构：
[Long Li-Ping; Liu Rong; Liu Yu; Lei Cun-Xi; Li Si-Jia] Hunan City Univ, Coll Chem & Environm Engn, Yiyang 413000, Peoples R China.;[Liu Rong; Wu Zhao-Yang] Hunan Univ, State Key Lab Chemo Biosensing & Chemometr, Changsha 410082, Hunan, Peoples R China.
通讯机构：
[Long Li-Ping] H;Hunan City Univ, Coll Chem & Environm Engn, Yiyang 413000, Peoples R China.
关键词：
分子印迹;桑色素;电化学传感器;电聚合
摘要：
以邻氨基酚(o-AP)为功能单体,桑色素为模板分子,基于分子间的相互作用力,在金电极表面电聚合制备具有特异性识别孔穴的桑色素分子印迹传感器膜。采用循环伏安法(CV)、差分脉冲伏安法(DPV)等研究了分子印迹膜的性能和分子印迹效应。探索了聚合膜配比及聚合扫描圈数对传感器性能的影响,优化了洗脱时间和印迹时间。比较了此传感器对其结构相似物的选择性响应,发现其对桑色素检测具有良好的选择性。在最佳实验条件下,此传感器对桑色素浓度定量测定范围为0.05 ~ 1.70 μmol /L,线性方程为I(μA)= 1.0800lgc(mol /L)+ 9.3599,R= 0.9934,检出限为0.01 μmol /L。用此传感器测定黑茶样品中桑色素的含量,加标回收率为104.0% ~ 108.0%。
语种：
中文
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A ratiometric fluorescence sensor for Fe3+ based on FRET and PET processes
作者：
Hu, Yongjun;Wang, Jiaoliang* ;Long, Liping;Xiao, Xiaoming
期刊：
LUMINESCENCE ,2016年31(1):16-21 ISSN：1522-7235
通讯作者：
Wang, Jiaoliang
作者机构：
[Wang, Jiaoliang; Long, Liping; Hu, Yongjun] Univ South China, Coll Chem & Chem Engn, Hengyang, Hunan, Peoples R China.;[Wang, Jiaoliang] Hunan City Univ, Coll Chem & Environm Engn, Yiyang, Hunan, Peoples R China.;[Wang, Jiaoliang] Hunan Univ, State Key Lab Chemo Biosensing & Chemometr, Changsha 410082, Hunan, Peoples R China.;[Xiao, Xiaoming] Hunan Normal Univ, Key Lab Chem Biol & Tradit Chinese Med Res, Minist Educ, Changsha, Hunan, Peoples R China.
通讯机构：
[Wang, Jiaoliang] U;Univ South China, Coll Chem & Chem Engn, Hengyang, Hunan, Peoples R China.
关键词：
Emission spectroscopy;Emission spectrums;Fe 3+;High sensitivity;Large shifts;PET process;Ratiometric;Ratiometric fluorescence sensors;Rhodamine;Rhodamine/coumarin;Synthesised;Forster resonance energy transfer;coumarin;coumarin derivative;ferric ion;fluorescent dye;rhodamine;chemical structure;chemistry;fluorescence resonance energy transfer;positron emission tomography;synthesis;Coumarins;Ferric Compounds;Fluorescence Resonance Energy Transfer;Fluorescent Dyes;Molecular Structure;Positron-Emission Tomography;Rhodamines
摘要：
A rhodamine/coumarin-based ratiometric fluorescent Fe3+ sensor has been designed and synthesized. The sensor exhibits a good response to Fe3+ ions with high sensitivity, selectivity and a large shift in the emission spectra (>100 nm), which shows Fe3+-induced FRET OFF-ON and PET ON-OFF behavior. Copyright © 2015 John Wiley & Sons, Ltd. Copyright © 2015 John Wiley & Sons, Ltd.
语种：
英文
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A graphene/ionic liquid modified selenium-doped carbon paste electrode for determination of copper and antimony
作者：
Liu, Rong;Lei, Cunxi* ;Zhong, Tongsheng;Long, Liping;Wu, Zhaoyang;...
期刊：
ANALYTICAL METHODS ,2016年8(5):1120-1126 ISSN：1759-9660
通讯作者：
Lei, Cunxi
作者机构：
[Zhong, Tongsheng; Zhang, Qi; Lei, Cunxi; Liu, Rong; Long, Liping] Hunan City Univ, Coll Chem & Environm Engn, Yiyang 413000, Peoples R China.;[Wu, Zhaoyang; Liu, Rong; Huan, Shuangyan] Hunan Univ, Coll Chem & Chem Engn, State Key Lab Chemo Biosensing & Chemometr, Changsha 410082, Hunan, Peoples R China.
通讯机构：
[Lei, Cunxi] H;Hunan City Univ, Coll Chem & Environm Engn, Yiyang 413000, Peoples R China.
摘要：
A graphene (GN) and ionic liquid (IL) modified selenium-doped carbon paste electrode (GN/IL/Se/CPE) was established to simultaneously determine trace Cu(ii) and Sb(iii) by differential pulse voltammetry (DPV). Several parameters which affect the stripping current response were investigated and optimized, including the proportion of Se powder, concentration of hydrochloric acid, deposition time and deposition potential. The DPV curves were recorded by simultaneous deposition of Cu(ii) and Sb(iii) at -0.4 V for 50 s in a supporting electrolyte solution HCl of 0.30 mol L-1. Under the optimized conditions, the GN/IL/Se/CPE sensor has a good linear response in the range of 2.0 × 10-6 to 7.0 × 10-5 mol L-1 for Cu(ii) and 2.0 × 10-6 to 4.0 × 10-5 mol L-1 for Sb(iii). The detection limits were 6.6 × 10-7 mol L-1 for Cu(ii) and 4.3 × 10-7 mol L-1 for Sb(iii). The sensor showed favorable stability and higher sensitivity. The present work extends the scope of these devices as mercury-free sensors and can be used to detect Cu(ii) and Sb(iii) simultaneously. © The Royal Society of Chemistry 2016.
语种：
英文
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Facile synthesis, characterization and visible-light photocatalytic performance of Ag3PO4
作者：
Li Lin;Manhong Huang;Liping Long;Zhe Sun;Donghui Chen
期刊：
Asian Journal of Chemistry ,2014年26(20):7055-7060 ISSN：0970-7077
通讯作者：
Manhong, H.
作者机构：
[Zhe Sun; Manhong Huang] School of Environmental Science and Engineering, Donghua University, Shanghai, 201620, P.R., China;[Zliping L.] School of Chemical and Environmental Engineering, Hunan City University, Yiyang, 413000, China;Shanghai Institute of Technology, Shanghai, 200235, P.R., China;[Donghui Chen] School of Environmental Science and Engineering, Donghua University, Shanghai, 201620, P.R., China, Shanghai Institute of Technology, Shanghai, 200235, P.R., China;[Liping Long] School of Environmental Science and Engineering, Donghua University, Shanghai, 201620, P.R., China, School of Chemical and Environmental Engineering, Hunan City University, Yiyang, 413000, China
通讯机构：
[Manhong, H.] S;School of Environmental Science and Engineering, China
关键词：
Ag3PO4;Photocatalyst;Tetracycline;Visiblel light
摘要：
Silver(I) phosphate (Ag3PO4) photocatalysts were synthesized via a facile solid phase ion-exchange method, X-ray diffraction, scanning electron microscopy and UV-visible diffuse reflectance spectroscopy (DRS) were used to characterize the as-prepared samples. The photocatalytic performance and mechanism of as-prepared samples were investigated by the degradation of tetracyclines in aqueous solution under visible light irradiation (λ > 420 nm). The results indicated that the as-prepared samples were irregular spherical morphology with paticle size of 0.5-1.5 μm and exibited strong light absorbance in the visible light region. The superior photocatalytic activity and removal efficiency of total organic carbon (TOC) were also observed. The mechanism expriment results demonstrated that the O_2~(·-), ~·OH and hole were all reactive oxygen species and the possible photocatalytic mechanism was proposed.
语种：
英文
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掺杂羟基磷灰石和石墨烯的碳糊电极测铅和镉
作者：
刘蓉;龙立平;胡拥军;呼晓增
作者机构：
湖南城市学院化学与环境工学院,湖南益阳,413000
会议名称：
第十二届全国电分析化学学术会议
会议时间：
2014-04-01
会议地点：
桂林
会议论文集名称：
第十二届全国电分析化学学术会议论文集
关键词：
水质监测;铅元素;镉元素;碳糊电极;羟基磷灰石;石墨烯
摘要：
本文主要研究掺杂羟基磷灰石和石墨烯碳糊电极在差分脉冲伏安法(DPV)的条件下同时测定Pb2+和Cd2+,对实验参数:掺杂羟基磷灰石和石墨烯的比例、盐酸的浓度、沉积时间和沉积电位进行了优化.最优的实验条件为:羟基磷灰石和石墨烯比例分别为20％和2％,盐酸浓度0.24mol/L,沉积时间50s,沉积电位-1.3V.在最优实验条件下用DPV法对不同浓度的Pb2+和Cd2+进行了同时测定,Pb2+和Cd2+的线性方程分别为IPb2+(A)=-0.06306-0.05539 C(mol/L)(R=-0.9920);ICd2+(A)=-0.1100-0.01514C(mol/L)(R=-0.9996),富集时间为150s,Pb2+、Cd2+的检出限分别为:2.20110-7mol/L;1.35210-6mol/L,回收率分别为:105.6％和103.3％.
语种：
中文
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PREVENTATIVE EFFECTS OF FUZHUAN BRICK TEA EXTRACTS ON TETRAOXYPYRIMIDINE - INDUCED EXPERIMENTAL DIABETES
作者：
Liu, S. Q.;Zhao, Y. L.;Peng, Y. X.;Hu, Z. Y.;Long, L. P.;...
期刊：
BASIC & CLINICAL PHARMACOLOGY & TOXICOLOGY ,2014年115(SUPPL-4):7-7 ISSN：1742-7835
作者机构：
[Long, L. P.; Peng, Y. X.; Liu, S. Q.; Zhao, Y. L.; Hu, Z. Y.] Hunan City Univ, Coll Chem & Environm Engn, Yiyang, Hunan, Peoples R China.;[Yang, X. P.] Univ Colorado Denver, Sch Med, Dept Med, Div Med Oncol, Aurora, CO USA.;[Weir, T.] Colorado State Univ, Dept Food Sci & Nutr, Ft Collins, CO 80523 USA.
语种：
英文
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黑茶乙醇提取物以及其抗氧化性的研究
作者：
刘蓉;刘石泉;龙立平;赵运林;张蓉
期刊：
湖南城市学院学报(自然科学版) ,2014年23(1):52-55 ISSN：1672-7304
作者机构：
湖南城市学院化学与环境工学院,湖南益阳,413000;[张蓉; 龙立平; 刘蓉; 刘石泉; 赵运林] 湖南城市学院
关键词：
黑茶;乙醇提取物;抗氧化性;自由基;分光光度法
摘要：
目的：研究黑茶的抗氧化性作用.方法：采用溶液超声波提取法提取出黑茶的乙醇提取物,再用分光光度法测定不同浓度的黑茶乙醇提取物对羟基自由基、DPPH自由基的抑制率以及还原能力.结果：在一定范围内,随着黑茶提取物的含量增加其对自由基的抑制作用以及还原能力都逐渐增强.当提取液体积为0.20 mL时,提取液对羟基自由基的抑制达到最大为51.70％.在黑茶提取液体积达到0.16 mL时,其对DPPH自由基的抑制达到最高为87.44％.黑茶提取物的还原能力,在一定浓度范围内呈现正相关性A=0.040 3＋2.007 4V,相关系数为0.999 6.结论：黑茶乙醇提取物具有较好的抗氧化性.
语种：
中文
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