疏水/亲水大孔聚二乙烯基苯/聚（N-2-氨基乙基丙烯酰胺）IPN树脂的合成及对水杨酸吸附性能研究
SCI-E CSCD
作者：
Xiao Guqing;Gao Shuqin;Xie Xianglin;Xu Mancai
期刊：
高分子学报 ,2008年(11):1025-1030 ISSN：1000-3304
通讯作者：
Xiao, GQ
作者机构：
[Xiao Guqing; Gao Shuqin; Xie Xianglin; Xu Mancai] Hunan Normal Univ, Coll Chem & Chem Engn, Changsha 410081, Hunan, Peoples R China.;[Xiao Guqing] Hunan City Univ, Coll Chem & Environm Engn, Yiyang 413000, Peoples R China.
通讯机构：
[Xiao, GQ ] Hunan Normal Univ, Coll Chem & Chem Engn, Changsha 410081, Hunan, Peoples R China.;Hunan Normal Univ, Coll Chem & Chem Engn, Changsha 410081, Hunan, Peoples R China.
关键词：
疏水/亲水;水杨酸;吸附
摘要：
采用分步悬浮聚合法制备了聚二乙烯基苯/聚丙烯酸甲酯（PDVB/PMA）大孔互穿聚合物网络,将其中的聚丙烯酸甲酯用乙二胺氨解,合成了具有疏水/亲水性能的聚二乙烯基苯/聚（N-2-氨基乙基丙烯酰胺）（PDVB/PNAEAM）大孔互穿聚合物网络（IPN）;测定了该树脂的孔结构、含水量、弱碱交换量和溶胀性能;测定了该树脂对水杨酸在不同温度下的吸附等温线,利用热力学函数关系计算出了吸附焓、自由能和熵.推测PDVB/PNAEAM IPN树脂中疏水性的PDVB一网具有疏水作用吸附能力、亲水性的PNAEAM一网具有氢键作用吸附能力.动态吸附及脱附实验表明湿态PDVB/PNAEAM IPN树脂对水溶液中水杨酸的饱和吸附量达到46.1mg/mL.树脂可以通过4%NaOH溶液再生.PDVB/PNAEAM IPN树脂在分离工业废水中水杨酸等芳香有机酸有良好的应用前景.
语种：
中文
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2-氨基吡啶修饰的聚苯乙烯树脂对2,4-D的吸附性能
作者：
孟秋冬;肖谷清;宋娟娟;李必才
期刊：
离子交换与吸附 ,2019年(01):41-49 ISSN：1001-5493
作者机构：
湖南城市学院图书馆;湖南城市学院材料与化学工程学院
关键词：
2-氨基吡啶修饰的聚苯乙烯树脂;吸附
摘要：
氯甲基聚苯乙烯和2-氨基吡啶发生亲核取代反应,合成2-氨基吡啶修饰的聚苯乙烯树脂(简记为JX-08),以XAD-4树脂为参照,研究JX-08树脂对水溶液中2,4-D的吸附性能。实验结果表明,JX-08树脂在较宽的pH值范围(pH值在2~11)对2,4-D的吸附量大,XAD-4树脂在pH值小于2时对2,4-D的吸附量大;JX-08树脂对2,4-D的吸附符合Freundlich方程模型,XAD-4树脂对2,4-D的吸附符合Langmuir方程模型;当2,4-D流出液浓度为上样浓度的1%时,JX-08树脂和XAD-4树脂对2,4-D的吸附量分别为148.2mg/mL和40.5mg/m L。JX-08树脂和XAD-4树脂吸附的2,4-D可分别用6.5BV 2mol/L NaOH和6.5BV C2H5OH解吸。吸附机理表明,XAD-4树脂吸附2,4-D以疏水作用为主要推动力,而JX-08树脂对2,4-D的吸附存在阴离子交换和疏水作用,且阴离子交换对JX-08树脂吸附2,4-D的贡献大于疏水作用对JX-08树脂吸附2,4-D的贡献。
语种：
中文
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Adsorption of Salicylic Acid in Aqueous Solution by a Water-Compatible Hyper-Cross-Linked Resin Functionalized with Amino-Group
WOS被引频次：17
SCI-E EI
作者：
Xiao, Gu-Qing* ;Li, Hua;Xu, Man-Cai
期刊：
Journal of Applied Polymer Science ,2013年127(5):3858-3863 ISSN：0021-8995
通讯作者：
Xiao, Gu-Qing
作者机构：
[Xiao, Gu-Qing] Hunan City Univ, Coll Chem & Environm Engn, Yiyang 413000, Hunan, Peoples R China.;[Li, Hua; Xu, Man-Cai] Hunan Normal Univ, Coll Chem & Chem Engn, Changsha 410081, Hunan, Peoples R China.
通讯机构：
[Xiao, Gu-Qing] Hunan City Univ, Coll Chem & Environm Engn, Yiyang 413000, Hunan, Peoples R China.
关键词：
synthesis;functionalization of polymers;salicylic ACID;adsorption
摘要：
On account of the high toxicity of nitrobenzene, 1,2‐dichloroethane was used as solvent. A novel water‐compatible hyper‐cross‐linked resin functionalized with amino‐group (denoted as GQ‐04) was synthesized to remove salicylic acid (SA) in aqueous solution. The maximum adsorption capacity of SA onto GQ‐04 was observed at pH of 1.88. The adsorption capacity increased with the increasing salt concentration. The adsorption kinetic data obeyed the pseudo‐second‐order rate equation and the adsorption isotherms can be characterized by Freundlich model. The intraparticle diffusion was the main rate‐controlling step. The saturated adsorption quantity of SA was up to 119.9 mg·mL‐1 according to the dynamic adsorption at 293 K. The resin could be regenerated by the 6 BV mixed solution of 80% ethanol and 0.5 mol/L NaOH. The size matching and hydrogen bonding between GQ‐04 and SA and the micropore structure resulted in the larger adsorption capacity in comparison with XAD‐4 and H103 resin. © 2012 Wiley Periodicals, Inc. J. Appl. Polym. Sci., 2013
语种：
英文
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Adsorption of phenol onto four hyper-cross-linked polymeric adsorbents: Effect of hydrogen bonding receptor in micropores on adsorption capacity
WOS被引频次：17
SCI-E EI
作者：
Xiao, Guqing* ;Wen, Ruimin;You, Peiqing;Wu, Dan
期刊：
Microporous and Mesoporous Materials ,2017年239:40-44 ISSN：1387-1811
通讯作者：
Xiao, Guqing
作者机构：
[Wen, Ruimin; Xiao, Guqing; You, Peiqing; Wu, Dan] Hunan City Univ, Coll Chem & Environm Engn, Yiyang 413000, Peoples R China.
通讯机构：
[Xiao, Guqing] Hunan City Univ, Coll Chem & Environm Engn, Yiyang 413000, Peoples R China.
关键词：
Hyper-cross-linked adsorbent;Hydrogen bonding receptor;Micropores;Density functional theory
摘要：
Different functional group modified hyper-cross-linked polymeric adsorbents H103, GQ-1, GQ-2 and GQ-5 were synthesized from macroporous crosslinked chloromethylated styrene-divinylbenzene copolymers. Phenol was selected as a hydrogen bonding donator. The object of this work was to explore the effect of hydrogen bonding receptor in micropores of adsorbent on adsorption capacity. Results showed the BET surface area and pore volume followed the order H103 > GQ-5 > GQ-2 > GQ-1 while the adsorption capacity of phenol onto the four hyper-cross-linked polymeric adsorbents followed the order GQ-1 > GQ-2 > GQ-5 > H103. The density functional theory indicated that hydrogen bonding receptor in micropores of the adsorbents was a crucial factor for the adsorption capacity order. ©2016 Elsevier Inc.
语种：
英文
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Adsorption performance of salicylic acid on a novel resin with distinctive double pore structure
WOS被引频次：19
SCI-E EI Medline
作者：
Xiao, Guqing* ;Wen, Ruiming;Liu, Aijiao;He, Guowen;Wu, Dan
期刊：
Journal of Hazardous Materials ,2017年329:77-83 ISSN：0304-3894
通讯作者：
Xiao, Guqing
作者机构：
[Xiao, Guqing; Wen, Ruiming; Liu, Aijiao; He, Guowen; Wu, Dan] Hunan City Univ, Coll Chem & Environm Engn, Yiyang 413000, Peoples R China.
通讯机构：
[Xiao, Guqing] Hunan City Univ, Coll Chem & Environm Engn, Yiyang 413000, Peoples R China.
关键词：
Double pore structure;Multifunctional adsorption mechanism;Salicylic acid;Adsorption
摘要：
Two approaches were used to synthesize two resins with different pore structures. In one way, the [sbnd]CH<inf>2</inf>Cl groups in macroporous chloromethylated polystyrene resin were transformed to methylene bridges, and achieved a hypercrosslinked resin with plentiful micropores (denoted GQ-06). In the other way, 50% of the [sbnd]CH<inf>2</inf>Cl groups in chloromethylated polystyrene resin was used to produce micropores, while the residual 50% of the [sbnd]CH<inf>2</inf>Cl groups was reacted with 2-aminopyridine, and prepared another resin with double pore structure of hypercrosslinked resin and macroporous resin (denoted GQ-11). The adsorption of salicylic acid (SA) on GQ-11 was investigated using GQ-06 as the reference adsorbent. The effect of pH on the adsorption of SA on GQ-06 was consistent with the dissociation curve of SA. The maximum adsorption capacity of SA on GQ-11 was observed at the solution pH of 2.64. The greater adsorption rate of SA on GQ-11 than that of GQ-06 was attributed to its double pore structure. The multifunctional adsorption mechanism of anion exchange and hydrophobic interaction resulted in the larger equilibrium capacity of SA on GQ-11 than that of GQ-06. GQ-06 and GQ-11 could be regenerated by absolute alcohol and 80% of alcohol −0.5 mol/L of sodium hydroxide aqueous solution, respectively. ©2017 Elsevier B.V.
语种：
英文
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Effects of the steric hindrance of micropores in the hyper-cross-linked polymeric adsorbent on the adsorption of p-nitroaniline in aqueous solution
WOS被引频次：17
SCI-E EI Medline
作者：
Xiao, Guqing* ;Wen, Ruimin;Wei, Dongmei;Wu, Dan
期刊：
Journal of Hazardous Materials ,2014年280:97-103 ISSN：0304-3894
通讯作者：
Xiao, Guqing
作者机构：
[Wen, Ruimin; Xiao, Guqing; Wei, Dongmei; Wu, Dan] Hunan City Univ, Coll Chem & Environm Engn, Yiyang 413000, Peoples R China.
通讯机构：
[Xiao, Guqing] Hunan City Univ, Coll Chem & Environm Engn, Yiyang 413000, Peoples R China.
关键词：
Hyper-cross-linked polymeric adsorbent;Micropore;Steric hindrance;Adsorption;p-Nitroaniline
摘要：
A hyper-cross-linked polymeric adsorbent with "CH<inf>2</inf>phenolCH<inf>2</inf>" as the cross-linked bridge (denoted GQ-05), and another hyper-cross-linked polymeric adsorbent with "CH<inf>2</inf>p-cresolCH<inf>2</inf>" as the cross-linked bridge (denoted GQ-03) were synthesized to reveal the effect of the steric hindrance of micropores in the hyper-cross-linked polymeric adsorbent on adsorption capacity and adsorption rate of p-nitroaniline (PNA) from aqueous solution. The results of adsorption kinetics indicated the order of the adsorption rate GQ-05>GQ-03. The pseudo-first-order rate equation could describe the entire adsorption process of PNA onto GQ-05 while the equation characterized the adsorption process of GQ-03 in two stages. The order of the adsorption capacity GQ-05>GQ-03 was demonstrated by thermodynamic analysis and dynamic adsorption. The steric hindrance of micropores in the hyper-cross-linked polymeric adsorbent was a crucial factor for the order of the adsorption capacity and adsorption rate. ©2014 Elsevier B.V.
语种：
英文
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疏水/亲水大孔PDVB/PAEM IPN 树脂对香兰素的吸附性能
WOS被引频次：6
SCI-E CSCD
作者：
Xiao Gu-Qing;Me Xiang-Lin;Xu Man-Cai*
期刊：
物理化学学报 ,2009年25(1) ISSN：1000-6818
通讯作者：
Xu Man-Cai
作者机构：
[Xu Man-Cai; Xiao Gu-Qing; Me Xiang-Lin] Hunan Normal Univ, Coll Chem & Chem Engn, Changsha 410081, Hunan, Peoples R China.;[Xiao Gu-Qing] Hunan City Univ, Coll Chem & Environm Engn, Yiyang 413000, Hunan, Peoples R China.
通讯机构：
[Xu Man-Cai] Hunan Normal Univ, Coll Chem & Chem Engn, Changsha 410081, Hunan, Peoples R China.
关键词：
疏水/亲水;香兰素;吸附;热力学;动力学
摘要：
采用分步悬浮聚合法制备了具有疏水性能的聚二乙烯基苯(polydivinyibenzene,PDVB)为第一网,具有亲水性能的聚丙烯酰乙二胺(polyacrylethylenediamine,PAEM)为第二网的疏水/亲水大孔聚二乙烯基苯/聚丙烯酰乙二胺(PDVB/PAEM)互穿聚合物物内网络(interpenetrating polymer networks,IPN),研究这类疏水/亲水IPN组成的树脂对吸附质的吸附热力学和吸附动力学;测定了该树脂对香兰素在不同温度下的吸附等温线,吸附等温线符合Freundlich 等温吸附方程,利用热力学函数关系计算出了吸附焓、自由能和熵变.实验表明,PDVB/PAEMIPN树脂中疏水性的 PDVB 网具有疏水作用吸附能力,亲水性的PAEM网具有氧键作用吸附能力.吸附动力学数据符合 Lagergren 二级速率方程,颗粒内扩散是吸附速率的主要控制步骤,可口采用 HSDM 模型加以描述.
语种：
中文
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邻氨基吡啶修饰的复合孔结构树脂对2,4-D酸的吸附性能
作者：
胡银;肖谷清;杨勇;黎健坤;宋娟娟
期刊：
离子交换与吸附 ,2018年(06):490-499 ISSN：1001-5493
作者机构：
湖南城市学院材料与化学工程学院黑茶金花湖南省重点实验室
关键词：
复合孔结构;多重吸附机理;2,4-D酸
摘要：
将氯球中-CH2Cl转化为亚甲基交联桥,合成微孔丰富的超高交联树脂（命名为JX-06）。同时将氯球中50%的-CH2Cl转化为亚甲基交联桥,50%的-CH2Cl与邻氨基吡啶反应,合成既具有超高交联树脂孔结构和大孔树脂孔结构,又具有邻氨基吡啶功能基的复合孔结构树脂（命名为JX-11）,对比研究JX-06树脂和JX-11树脂对2,4-D酸的吸附性能。实验结果表明,JX-06树脂吸附2,4-D酸的吸附量随p H值的变化规律与2,4-D酸分子比（2,4-D酸分子在2,4-D酸分子和2,4-D酸离子总和中所占的比）随p H值的变化规律相一致。JX-11树脂在p H值为3.23时对2,4-D酸的吸附量最大。疏水效应和阴离子交换的多重吸附导致JX-11树脂对2,4-D酸的吸附量大于JX-06树脂。复合孔结构使JX-11树脂比JX-06树脂对2,4-D酸有更高的吸附速率。经5次吸附解吸循环,JX-06树脂对2,4-D酸的吸附量略有减小,而JX-11树脂对2,4-D酸的吸附量则保持稳定。
语种：
中文
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茶多糖的提取研究进展
作者：
游沛清;冯小萍;李滔滔;文瑞明;肖谷清
期刊：
现代食品 ,2018年(17):174-176 ISSN：2096-5060
作者机构：
湖南城市学院材料与化学工程学院
关键词：
茶;茶多糖;提取方法
摘要：
评述了采用水浸法、酶辅助提取法、微波辅助提取法、超声波辅助提取法、树脂法和超临界萃取法提取茶多糖的方法,对茶多糖的研究前景作了展望,为今后此类化合物的研究、开发提供可借鉴的依据.
语种：
中文
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LVJ纳滤膜对磺胺二甲基嘧啶截留性能
CSCD
作者：
肖谷清;周贤勇;文瑞明;尹志芳
期刊：
环境工程学报 ,2015年(1):230-234 ISSN：1673-9108
作者机构：
[肖谷清; 周贤勇; 文瑞明; 尹志芳] 湖南城市学院化学与环境工程学院
关键词：
LVJ纳滤膜;磺胺二甲基嘧啶;截留率
摘要：
用LVJ-NF102聚酰胺纳滤膜在LJ-2540ST卷式膜中试设备中进行纳滤截留水体中磺胺二甲基嘧啶实验,考察操作时间、操作压力、磺胺二甲基嘧啶浓度和离子强度等因素对纳滤膜截留磺胺二甲基嘧啶的影响。结果表明,LVJ纳滤膜对磺胺二甲基嘧啶的截留率100 min后基本稳定;随操作压力的增加,LVJ纳滤膜通量和对磺胺二甲基嘧啶的截留率都增大;随着溶液中磺胺二甲基嘧啶浓度的增加,LVJ纳滤膜通量下降,对磺胺二甲基嘧啶的截留率先增大后维持不变;随溶液中离子强度的增加,LVJ纳滤膜通量和对磺胺二甲基嘧啶的截留率都减小。在磺胺二甲基嘧啶浓度为28.2 mg/L、操作压力为0.4 MPa条件下,LVJ纳滤膜5 min可使溶液中磺胺二甲基嘧啶截留82.7%。
语种：
中文
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Synthesis of the hydrophobic-hydrophilic macroporous poly divinylbenzene/poly(sodium acrylate) IPN resin and adsorption performance for berberine
WOS被引频次：14
SCI-E EI
作者：
Xiao, Guqing;Gao, Shuqin;Xie, Xianglin;Xu, Mancai*
期刊：
Polymers for Advanced Technologies ,2009年20(12):1157-1162 ISSN：1042-7147
通讯作者：
Xu, Mancai
作者机构：
[Xu, Mancai; Gao, Shuqin; Xiao, Guqing; Xie, Xianglin] Hunan Normal Univ, Coll Chem & Chem Engn, Changsha 410081, Hunan, Peoples R China.;[Xiao, Guqing] Hunan City Univ, Coll Chem & Environm Engn, Yiyang 413000, Peoples R China.
通讯机构：
[Xu, Mancai] Hunan Normal Univ, Coll Chem & Chem Engn, Changsha 410081, Hunan, Peoples R China.
关键词：
hydrophobic–hydrophilic;PDVB/PNaA IPN resin;synthesis;berberine;adsorption
摘要：
The macroporous polydivinylbenzene/poly(methyl acrylate) interpenetrating polymer network (PDVB/PMA IPN) was prepared by the sequential suspension polymerization method, and was modified to be hydrophobic-hydrophilic macroporous polydivinylbenzene/poly (sodium acrylate) IPN (PDVB/PNaA IPN) by converting the PMA to PNaA under the condition of base. The effects of different mass ratio of the two networks and different cross-linking degree of the second network on the pore structure and adsorption capacity of PDVB/PNaA IPN resin were studied. The PDVB/PNaA IPN resin whose adsorption quantity is the biggest was chosen to study further. The pore structure, the weak acid exchange capacity, the water retention capacity, and the swelling ability of PDVB/PNaA IPN resin were measured. The study focused on the adsorption isotherms of berberine at different temperatures. Isosteric adsorption enthalpy, adsorption Gibbs free energies can be calculated according to tSh1ermodynamic functions. The results show that the saturated adsorption quantity of berberine is up to 109.4 mg ml<sup>-1</sup> (wet resin) by the way of dynamic adsorption and desorption experiment. The resin could be reused by the mixture with 0.5% sodium chloride and 80% ethanol. On the one hand the hydrophobic PDVB in the PDVB/PNaA IPN resin has the ability of adsorption using π-πinteraction, and on the other hand the hydrophilic PNaA in the PDVB/PNaA IPN resin has the ability of adsorption using ion exchange interaction. An important conclusion can be drawn that the PDVB/PNaA IPN resin has a promising application prospect in extracting and separating quaternary ammonium type alkaloids such as berberine. ©2009 John Wiley &Sons, Ltd.
语种：
英文
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Cu(Ⅱ)-阿莫西林体系的荧光特性及Cu(Ⅱ)的含量测定
CSCD
作者：
龙立平;谌委菊;肖谷清;钟桐生
期刊：
中国抗生素杂志 ,2011年(8):606-609 ISSN：1001-8689
通讯作者：
Long, L.-P.
作者机构：
湖南城市学院化学与环境工程院,益阳,413049;[龙立平; 谌委菊; 肖谷清; 钟桐生] 湖南城市学院
通讯机构：
College of Chemistry and Environmental Engineering, Hunan City University, China
关键词：
荧光光度法;荧光熄灭;阿莫西林;铜(Ⅱ)
摘要：
目的 建立荧光光度法测定实际样品中铜离子的含量。方法 基于铜离子对阿莫西林的荧光有显著的熄灭作用，建立了荧光法快速测定铜离子含量的新方法。结果 铜离子与阿莫西林发生配合反应，配合物的组成比为1:2，将该方法用于水样中铜离子的测定，铜离子浓度的线性范围为1．00×10~(-6)~5．00×10~(-2)mol／L，检出限为1．87×10~(-7)mol／L。样品回收率为 94．0％-106．5％。结论该方法简便、快速、准确.
语种：
中文
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2-氨基吡啶修饰的超高交联树脂对水杨酸的吸附性能
EI CSCD
作者：
文瑞明;游沛清;刘爱姣;肖谷清
期刊：
中南大学学报. 自然科学版 ,2016年(3):724-729 ISSN：1672-7207
通讯作者：
Wen, Ruiming(wenruiming@sohu.com)
作者机构：
[刘爱姣; 游沛清; 肖谷清; 文瑞明] College of Chemistry and Environmental Engineering, Hunan City University, Yiyang, 413000, China
通讯机构：
College of Chemistry and Environmental Engineering, Hunan City University, Yiyang, China
关键词：
2-氨基吡啶;超高交联树脂;水杨酸;吸附
摘要：
以二氯乙烷为溶剂,FeCl_3为催化剂,氯球发生Friedel-Crafts反应制备氯质量分数为6.32%的超高交联树脂(简记为GQ-09),将GQ-09树脂进一步用2-氨基吡啶修饰,制备超高交联树脂(简记为GQ-10),研究GQ-10树脂对水杨酸的吸附性能。实验结果表明:GQ-10树脂在pH为2.16时对水杨酸的吸附性能最好;GQ-10树脂对水杨酸的吸附等温线同时服从Langmuir方程和Freundlich方程;与树脂的孔结构对应,GQ-10树脂对水杨酸的吸附在2个时间段均适用准一级速率方程;GQ-10树脂对水杨酸的吸附既有阴离子交换,又存在酸碱作用和疏水作用。 GQ-10树脂吸附的水杨酸可用80%乙醇-0.5 mol/L NaOH解吸,解吸率为99.41%。
语种：
中文
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Electrochemical detection of dopamine in the presence of ascorbic acid using [email protected] 3 O 4 /nafion film modified electrode at a low working potential
WOS被引频次：2
SCI-E
作者：
He, Guowen* ;Wu, Dan;Xiao, Guqing
期刊：
International Journal of Electrochemical Science ,2015年:10093-10103 ISSN：1452-3981
通讯作者：
He, Guowen
作者机构：
[Xiao, Guqing; He, Guowen; Wu, Dan] Hunan City Univ, Coll Chem & Enviromental Engn, Yiyang 413000, Peoples R China.;[Xiao, Guqing; He, Guowen; Wu, Dan] Hunan City Univ, Inst Polymer Mat & Engn, Yiyang 413000, Peoples R China.
通讯机构：
[He, Guowen] Hunan City Univ, Coll Chem & Enviromental Engn, Yiyang 413000, Peoples R China.
关键词：
Dopamine;Low working potential;[email protected] Mn 3 O 4
摘要：
Graphene sheets (GS)@manganic manganous oxide (Mn 3 O 4 ) nanocomposites were prepared via a simple solvothermal process. [email protected] 3 O 4 /nafion (Nf) film modified glassy carbon electrode (GCE) was fabricated and applied for the detection of dopamine (DA) without the interference of ascorbic acid (AA) at the low working potential. The prepared nanocomposites ([email protected] 3 O 4 ) were characterized by X-ray diffraction (XRD) and fourier transform infrared spectroscopy (FT-IR), and the morphology of different electrodes was characterized by scanning electron microscopy (SEM). The electrochemical properties of the modified electrode (GCE|[email protected] 3 O 4 /Nf) were investigated by electrochemical impedance spectroscopy (EIS), cyclic voltammetry (CV) and current-time method (i-t curve). Under the optimized experimental conditions, the i-t curve showed a linear dependence on DA concentrations ranging from 1.0×10 -6 to 1.3×10 -3 M (R=0.9985) with a detection limit of 8.0×10 -8 M (S/N=3). The proposed method was used to detect DA in real pharmaceutical samples using the standard addition method without additional sample pre-treatment with satisfactory results, which showed great promise for screen-determination of DA in real samples. © 2015 The Authors.
语种：
英文
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三组分铜铬催化剂催化甘油制备羟基丙酮的研究
作者：
谢丹;李浔;龙立平;肖谷清;林立
期刊：
广州化工 ,2012年(12):93-95 ISSN：1001-9677
作者机构：
湖南城市学院化学与环境学院,湖南益阳,413000;长沙理工大学化学与生物工程学院,湖南长沙,410076;[肖谷清] 肖谷清;[谢丹] 谢丹;[龙立平] 龙立平
关键词：
生物质甘油;Cu-Cr-Zn催化剂;羟基丙酮
摘要：
用共沉淀法制备了Cu-Cr-Zn催化剂,考察了Cu/Cr/Zn比、沉淀温度、沉淀时pH值、煅烧温度等制备条件对甘油制备羟基丙酮的影响,并对催化剂进行了表征。结果表明：共沉淀法制备Cu-Cr-Zn催化剂具有较高的催化活性,而且其稳定性和再生能力较好,适宜催化剂制备条件为：Cu/Cr/Zn比为1∶1∶0.5,沉淀温度为70℃,沉淀时pH值为8.0,煅烧温度为400℃,羟基丙酮的选择性可达到90.2%。
语种：
中文
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Fast responsive fluorescence turn-on sensor for Cu2+ and its application in live cell imaging
WOS被引频次：20
SCI-E EI
作者：
Wang, Jiaoliang* ;Li, Hao;Long, Liping;Xiao, Guqing;Xie, Dan
期刊：
Journal of Luminescence ,2012年132(9):2456-2461 ISSN：0022-2313
通讯作者：
Wang, Jiaoliang
作者机构：
[Wang, Jiaoliang; Xie, Dan; Xiao, Guqing; Li, Hao; Long, Liping] Hunan City Univ, Coll Chem & Environm Engn, Yiyang 413000, Peoples R China.
通讯机构：
[Wang, Jiaoliang] Hunan City Univ, Coll Chem & Environm Engn, Yiyang 413000, Peoples R China.
关键词：
Fluorescence;Copper(II);Hydrolysis;Image
摘要：
A new effective fluorescent sensor based on rhodamine was synthesized, which was induced by Cu<sup>2</sup> in aqueous media to produce turn-on fluorescence. The new sensor 1 exhibited good selectivity for Cu<sup>2</sup> over other heavy and transition metal (HTM) ions in H<inf>2</inf>O/CH <inf>3</inf>CN(7:3, v/v). Upon addition of Cu<sup>2</sup>, a remarkable color change from colorless to pink was easily observed by the naked eye, and the dramatic fluorescence turn-on was corroborated. Furthermore, kinetic assay indicates that sensor 1 could be used for real-time tracking of Cu<sup>2</sup> in cells and organisms. In addition, the turn-on fluorescent change upon the addition of Cu<sup>2</sup> was also applied in bioimaging. ©2012 Elsevier B.V. All rights reserved.
语种：
英文
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Comparative adsorption of glyphosate from aqueous solution by 2-aminopyridine modified polystyrene resin, D301 resin and 330 resin: Influencing factors, salinity resistance and mechanism
WOS被引频次：20
SCI-E EI
作者：
Xiao, Guqing;Wen, Ruimin
期刊：
Fluid Phase Equilibria ,2016年411:1-6 ISSN：0378-3812
通讯作者：
Xiao, GQ
作者机构：
[Xiao, Guqing; Wen, Ruimin] Hunan City Univ, Coll Chem & Environm Engn, Yiyang 413000, Peoples R China.
通讯机构：
[Xiao, GQ ] Hunan City Univ, Coll Chem & Environm Engn, Yiyang 413000, Peoples R China.;Hunan City Univ, Coll Chem & Environm Engn, Yiyang 413000, Peoples R China.
关键词：
2-Aminopyridine modified polystyrene resin;Glyphosate;Adsorption;Salinity resistance
摘要：
Comparative adsorption of glyphosate from aqueous solution by 2-aminopyridine modified polystyrene resin (denoted GQ-08 resin), D301 resin and 330 resin was investigated with respect to influencing factors, salinity resistance and mechanism. Results showed the maximum adsorption capacity of glyphosate onto the three resins was observed at pH of 2.51, and glyphosate was adsorbed in the form of HOPO2-CH<inf>2</inf>NH2+CH<inf>2</inf>COOH and HOPO2-CH<inf>2</inf>NH2+CH<inf>2</inf>COO<sup>-</sup>. The adsorption capacity of glyphosate onto the three resins followed the order 330 resin >D301 resin >GQ-08 resin, consistent with their total exchange capability order. GQ-08 resin exhibited excellent salinity resistance. Salinity resistance of GQ-08 resin resulted from the hydrogen bonding for the adsorption of glyphosate, while 330 resin and D301 resin exhibited the single adsorption mechanism of anion exchange. ©2015 Elsevier B.V.
语种：
英文
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铁碳微电解/H2O2耦合工艺预处理水中砷的研究
作者：
彭映林;卿微;肖谷清;宋娟娟;方芳
期刊：
湖南城市学院学报(自然科学版) ,2018年(2):74-78 ISSN：1672-7304
作者机构：
[彭映林; 卿微; 肖谷清; 宋娟娟; 方芳] 湖南城市学院 材料与化学工程学院,湖南 益阳,413000
关键词：
砷;铁碳微电解;强化微电解
摘要：
采用铁碳微电解/H2O2耦合工艺预处理水溶液中砷,研究了溶液初始p H、铁碳球投加量、曝气流量、H2O2投加量、反应温度和初始总砷（TAs）浓度等因素对砷去除效果的影响﹒结果表明,在铁碳微电解体系中加入H2O2能明显提高水溶液中TAs和三价砷（As（Ⅲ））去除率﹒当溶液初始TAs和As（Ⅲ）浓度分别为539 mg/L和368 mg/L,溶液初始pH为2.5,铁碳球投加量为530 g/L,曝气流量为60 m L/min,H2O2投加量为2 m L,在15℃下曝气反应1 h时,溶液中TAs和As（Ⅲ）去除率分别达到61.94%和55.06%;然而,未加H2O2,在同样条件下处理,TAs和As（Ⅲ）去除率分别为47.07%和41.97%。
语种：
中文
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Effects of the hydrophobicity of adsorbate on the adsorption of salicylic acid and 5-sulfosalicylic acid onto the hydrophobic-hydrophilic macroporous polydivinylbenzene/polymethylacrylethylenediamine IPN
WOS被引频次：3
SCI-E EI
作者：
Xiao, Guqing* ;Wen, Ruiming;Wei, Dongmei
期刊：
Fluid Phase Equilibria ,2016年 ISSN：0378-3812
通讯作者：
Xiao, Guqing
作者机构：
[Xiao, Guqing; Wen, Ruiming; Wei, Dongmei] Hunan City Univ, Coll Chem & Environm Engn, Yiyang 413000, Peoples R China.
通讯机构：
[Xiao, Guqing] Hunan City Univ, Coll Chem & Environm Engn, Yiyang 413000, Peoples R China.
关键词：
Hydrophobic-hydrophilic;PDVB/PMAEM IPN;Salicylic acid;5-Sulfosalicylic acid;Adsorption
摘要：
Hydrophobic-hydrophilic macroporous polydivinylbenzene/polymethylacrylethylenediamine IPN (PDVB/PMAEM IPN) was synthesized indirectly through the strong forced compatibility. The effects of the hydrophobicity of adsorbate on the adsorption of salicylic acid and 5-sulfosalicylic acid onto the hydrophobic-hydrophilic PDVB/PMAEM IPN were investigated. PDVB/PMAEM IPN exhibited greater adsorption capacity of salicylic acid than that of 5-sulfosalicylic acid. The absolute values of Delta H, Delta G and Delta S of the adsorption of salicylic acid onto PDVB/PMAEM IPN were greater than those of 5-sulfosalicylic acid, indicating the adsorption of salicylic acid onto PDVB/PMAEM IPN was more welcome. Adsorption mechanism proved that greater adsorption capacity of salicylic acid onto PDVB/PMAEM IPN than that of 5-sulfosalicylic acid was attributed to the stronger hydrophobicity of salicylic acid. (C) 2016 Elsevier B.V. All rights reserved.
语种：
英文
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Efficient removal of aniline by a water-compatible microporous and mesoporous hyper-cross-linked resin and XAD-4 resin: A comparative study
WOS被引频次：32
SCI-E EI
作者：
Xiao, Guqing* ;Long, Liping
期刊：
Applied Surface Science ,2012年 ISSN：0169-4332
通讯作者：
Xiao, Guqing
作者机构：
[Xiao, Guqing; Long, Liping] Hunan City Univ, Coll Chem & Environm Engn, Yiyang 413000, Peoples R China.;[Xiao, Guqing] Nanjing Univ, Sch Environm, State Key Lab Pollut Control & Resource Reuse, Nanjing 210093, Jiangsu, Peoples R China.
通讯机构：
[Xiao, Guqing] Hunan City Univ, Coll Chem & Environm Engn, Yiyang 413000, Peoples R China.
关键词：
Hyper-cross-linked resin;XAD-4;Aniline;Adsorption
摘要：
A novel water-compatible microporous and mesoporous hyper-cross-linked resin modified with phenolic hydroxyl group (named as GQ-03) was synthesized to remove aniline in aqueous solution as compared with XAD-4. The maximum adsorption capacity of GQ-03 emerged at the molecular state for both aniline and p-cresol while the pH dependency trend of aniline adsorbed onto XAD-4 was accordant with the dissociation curve of aniline. The ionic strength influenced the adsorption obviously. The pseudo-first-order rate equation could describe the adsorption process of aniline onto GQ-03 in two stages while this equation could characterize the entire adsorption process of XAD-4. The adsorption isotherms could be correlated to the Freundlich model, higher KF and n values for GQ-03 than XAD-4. The breakthrough capacity and the total adsorption capacity of GQ-03 and XAD-4 was up to 47.2 mg mL−1 and 28.3 mg mL−1, 271.7 mg mL−1 and 115.6 mg mL−1, respectively. The size matching between the pore diameter of GQ-03 and the molecular size of aniline, and hydrogen bonding between GQ-03 and aniline resulted in the larger adsorption capacity.
语种：
英文
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