(1)The successful adsorption of glyphosate by modified shell powder/Ce-N-TiO2 and the formation of negatively charged inner layer complexes on the surface of modified shell powder/Ce-N-TiO2 were demonstrated by SEM, zeta potential, FT-IR and XPS characterization. (2)The effects of pH, contact time and dosing amount on the removal rate were analyzed by response surface analysis, which indicated that the interaction of two-two factors had significant effects on the adsorption and removal of glyphosate. (3)Modified shell powder/Ce-N-TiO2 adsorption of glyphosate was in accordance with the quasi-secondary kinetic model and Langmuir model, and the maximum adsorption amount was 66.98 mg/g. This paper is one of the phase results of the National Natural Science Foundation of China (No: 42071122), Hunan University Student Innovation and Entrepreneurship Training Program (S202111527011, S202011527003).