This work was supported by the National Natural Science Foundation of China (no. 20375012, 20075006, and 29975006), the Foundation for Ph.D Thesis Research (no. 20010532008), and the Foundation of Scientific Committee of Hunan Province.
机构署名:
本校为其他机构
院系归属:
材料与化学工程学院
摘要:
A highly selective and sensitive electrochemical sensor modified with carboxymethylated, beta-cyclodextrin (CM-beta-CDP) polymer film was fabricated for the determination of dopamine (DA) in the presence of ascorbic acid (AA). The electrochemical behavior of DA and AA at the chemically modified electrode was investigated by cyclic voltammetry (CV) and differential pulse voltammetry. The response mechanism of CM-beta-CDP film for DA was based on the combination of electrostatic and inclusion interaction of CM-beta-CDP for DA, which was distinguished from the response mechanism of the charged po...