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Highly efficient determination of metal ion in cosmetic samples by reversed-phase liquid-liquid microextraction based on green hydrophobic deep eutectic solvent

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成果类型:
期刊论文
作者:
Liu, Bangfu;Zhou, Le-zhou;He, Guo-wen;Wang, Chaoli
通讯作者:
Liu, BF
作者机构:
[Liu, Bangfu; Liu, BF] Hunan Elect Informat Ind Inst, Jiefangdonglu 51, Changsha 410000, Hunan, Peoples R China.
[Zhou, Le-zhou] Hunan Prevent & Treatment Inst Occupat Dis, Changsha 410007, Hunan, Peoples R China.
[He, Guo-wen] Hunan City Univ, Coll Mat & Chem Engn, Yiyang 413000, Hunan, Peoples R China.
[Wang, Chaoli] Air Force Mil Med Univ, Dept Pharm, Xian 710000, Shanxii, Peoples R China.
通讯机构:
[Liu, BF ] H
Hunan Elect Informat Ind Inst, Jiefangdonglu 51, Changsha 410000, Hunan, Peoples R China.
语种:
英文
关键词:
Hydrophobic deep eutectic solvents;Stripping back extraction;Complexation;Metal ions;Three-phase separation
期刊:
Analytical Sciences
ISSN:
0910-6340
年:
2024
卷:
40
期:
1
页码:
115-121
机构署名:
本校为其他机构
院系归属:
材料与化学工程学院
摘要:
In this paper, a green hydrophobic deep eutectic solvent (HDES) composed of menthol and hexanoic acid was employed to dissolve cosmetics containing Cd2+ and Cd2+ was extracted using an EDTA-2Na saturated solution, analyzed by FAAS. The study found that HDES-1 can be recycled and reused well; the stability constants of Cd2+ EDTA chelates play an important role in the extracting process; the optimum conditions were: the solubility of HDES-1 was 20 mL/g for cosmetic sample at an indoor temperature of around 10 degrees C; the dissolver-extractant ratio was 2:1; the LOD was 0.037 mg/kg; the RSD was...

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