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Synergistic effect between S and Te enhancing the electrochemical behavior of heteroatomic TeS-x cathodes in aqueous Zn–TeS batteries

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成果类型:
期刊论文
作者:
Chang, Ge;Hao, Yisu;Huang, Cong;Yang, Yujie;Qian, Yang;...
通讯作者:
Chen, Xiaohua;Hu, AP
作者机构:
[Chen, Xiaohua; Zhu, Dejian; Liu, Zhixiao; Huang, Cong; Hu, Aiping; Chang, Ge; Hu, AP; Yang, Yujie; Qian, Yang; Tang, Qunli; Hao, Yisu] Hunan Univ, Coll Mat Sci & Engn, Changsha 410082, Peoples R China.
[Liu, Zheng] Hunan City Univ, Coll Mat & Chem Engn, All Solid State Energy Storage Mat & Devices Key H, Yiyang 413000, Peoples R China.
通讯机构:
[Chen, XH; Hu, AP ] H
Hunan Univ, Coll Mat Sci & Engn, Changsha 410082, Peoples R China.
语种:
英文
关键词:
Chalcogen molecules;Heteroatomic TeS-x cathodes;Redox mechanism;Te–S bonds;Zinc–sulfur batteries
期刊:
Journal of Colloid and Interface Science
ISSN:
0021-9797
年:
2024
卷:
675
页码:
630-638
基金类别:
CRediT authorship contribution statement Ge Chang: Software, Resources, Project administration, Methodology, Investigation, Data curation, Conceptualization. Yisu Hao: Investigation. Cong Huang: Methodology, Investigation. Yujie Yang: Methodology, Investigation. Yang Qian: Investigation. Dejian Zhu: Resources. Zhixiao Liu: Software. Zheng Liu: acquisition. Qunli Tang: Formal analysis, Data curation. Xiaohua Chen: Investigation, acquisition, Formal analysis, Conceptualization. Aiping Hu: Investigation, Funding
机构署名:
本校为其他机构
院系归属:
材料与化学工程学院
摘要:
Aqueous Zn–S batteries (AZSBs) have garnered increasing attention in the energy storage field owing to their high capacity, energy density, and cost effectiveness. Nevertheless, sulfur (S) cathodes face challenges, primarily stemming from sluggish reaction kinetics and the formation of an irreversible byproduct (SO42−) during the charge, hindering the progress of AZSBs. Herein, Te–S bonds within S-based cathodes were introduced to enhance electron and ion transport and facilitate the conversion reaction from zinc sulfide (ZnS) to S. This was...

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