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Synthesis and microstructure of a novel graft copolymer from poly(vinylidene fluoride-chlorotrifluoroethylene-trifluoroethylene)

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成果类型:
期刊论文
作者:
He, Guowen;Li, Fenfang;Zhong, Tongsheng;Hao, Zeming;Li, Hengfeng*
通讯作者:
Li, Hengfeng
作者机构:
[Li, Fenfang; He, Guowen] Cent S Univ, Sch Chem & Chem Engn, Changsha 410083, Peoples R China.
[Zhong, Tongsheng; He, Guowen] Hunan City Univ, Coll Chem & Environm Engn, Yiyang 413000, Peoples R China.
[Li, Hengfeng; He, Guowen] Cent S Univ, Sch Mat Sci & Engn, Changsha 410083, Peoples R China.
[Hao, Zeming] Sany Heavy Ind Concrete Pump Inst, Changsha 410100, Hunan, Peoples R China.
通讯机构:
[Li, Hengfeng] C
Cent S Univ, Sch Mat Sci & Engn, Changsha 410083, Peoples R China.
语种:
英文
关键词:
atom transfer radical polymerization (ATRP);graft copolymer;microstructure;properties
期刊:
DESIGNED MONOMERS AND POLYMERS
ISSN:
1385-772X
年:
2015
卷:
18
期:
1
页码:
19-26
基金类别:
The authors would like to acknowledge the Natural Science Foundation of Hunan Province of China [NSF, grant number 13JJ4102]; and the Postdoctoral fund of Central South University of China [No. 126223] for financial support.
机构署名:
本校为其他机构
院系归属:
材料与化学工程学院
摘要:
A novel graft copolymer of poly(vinylidene fluoride-chlorotrifluoroethylene-trifluoroethylene)-graft-poly(6-((4-cyano-4-biphenyl)oxy) hexyl methacrylate) (P(VDF-CTFE-TrFE)-graft-PCBHM) using P(VDF-CTFE-TrFE) as the initiator was successfully synthesized via atom transfer radical polymerization. It was found that the crystallinity of resultant graft copolymer increased slightly after grafting from the P(VDF-CTFE-TrFE), and the crystalline regions in the graft copolymer contained more (β phase which has all-trans chain conformation) trans chain ...

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