Ternary deep eutectic Solvents-Based Three-Phase partitioning for speciation of Cr (Ⅲ) and Cr (Ⅵ) in edible liquid Oil: A promising method for substituting

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成果类型：

期刊论文

作者：

Liu, Bangfu;Zhou, Le-zhou;Deng, Xiaobin;Tian, Xiangrong;He, Guo-wen;...

通讯作者：

Zhou, LZ

作者机构：

[Deng, Xiaobin; Liu, Bangfu; Zhou, Le-zhou; Zhou, LZ] Hunan Prevent & Treatment Inst Occupat Dis, Changsha 410007, Hunan, Peoples R China.

[Tian, Xiangrong] Jishou Univ, Coll Chem & Chem Engn, Natl & Local United Engn Lab Integrat Utilizat Tec, Jishou 416000, Peoples R China.

[He, Guo-wen] Hunan City Univ, Coll Mat & Chem Engn, Yiyang 413000, Hunan, Peoples R China.

[Wang, Chaoli] Air Force Mil Med Univ, Dept Pharm, Xian 710000, Shaanxi, Peoples R China.

[Liu, Bangfu; Yang, Fan] Hunan Elect Informat Ind Inst, Changsha 410000, Hunan, Peoples R China.

通讯机构：

[Zhou, LZ ] H

Hunan Prevent & Treatment Inst Occupat Dis, Changsha 410007, Hunan, Peoples R China.

语种：

英文

关键词：

Deep eutectic solvents;Three-phase partitioning;Edible liquid oil;Speciation analysis of Chromium;Liquid -liquid microextraction

期刊：

Microchemical Journal

ISSN：

0026-265X

年：

2024

卷：

204

页码：

110965

DOI：

10.1016/j.microc.2024.110965

基金类别：

This work was supported by Hunan Provincial National Health Commission of China (No.202212065516) and Hunan Natural Science Foundation of China (No.2018JJ6021).

机构署名：

本校为其他机构

院系归属：

材料与化学工程学院

摘要：

In this paper, a novelty ternary deep eutectic solvents was prepared with choline chloride, ethylene glycol and glycerol. The pH value was adjust to develop three-phase for speciation of Cr (III) and Cr (VI) extract and separate in ganoderma lucidum spore oil based on ternary deep eutectic solvents. The results show that DES-4 has a good extraction of Cr (III) and Cr (VI), the sample-extraction ratio was 3:1, Cr (III) was protected by EDTA, all chromium ions in ganoderma lucidum spore oil was extracted by near 100 % in 2 times, Cr (III) and Cr (VI) was well separated by saturated buffer soluti...

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Ternary deep eutectic Solvents-Based Three-Phase partitioning for speciation of Cr (Ⅲ) and Cr (Ⅵ) in edible liquid Oil: A promising method for substituting

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