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Rice Hull Powder-Derived Activated Carbons with Plentiful N and P Species for Supercapacitor with Excellent Rate Capacitance Characteristics

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成果类型:
期刊论文
作者:
Yang, Fan-Ming*;Xiao, Yang;Long, Sheng;He, Guo-Wen
通讯作者:
Yang, Fan-Ming;He, GW
作者机构:
[Long, Sheng; He, Guo-Wen; Xiao, Yang; Yang, Fan-Ming] Hunan City Univ, Coll Mat & Chem Engn, Yiyang 413000, Hunan, Peoples R China.
[He, Guo-Wen; Yang, Fan-Ming] Hunan City Univ, Coll Hunan Prov, Key Lab Low Carbon & Environm Funct Mat, Yiyang 413000, Hunan, Peoples R China.
通讯机构:
[Yang, FM; He, GW ] H
Hunan City Univ, Coll Mat & Chem Engn, Yiyang 413000, Hunan, Peoples R China.
Hunan City Univ, Coll Hunan Prov, Key Lab Low Carbon & Environm Funct Mat, Yiyang 413000, Hunan, Peoples R China.
语种:
英文
关键词:
capacitors;density functional theory;nitrogen;phosphorus;porous carbons
期刊:
ChemNanoMat
ISSN:
2199-692X
年:
2025
页码:
2500296
基金类别:
Natural Science Foundation of Hunan Province [2025JJ70380]
机构署名:
本校为第一且通讯机构
院系归属:
材料与化学工程学院
摘要:
Porous carbons with plentiful nitrogen and phosphorus heteroatoms (CMs-N/P-n) derived from rice hull powder and melamine polyphosphate are synthesized for superior charge/discharge performance. In the amorphous CMs-N/P-n materials, a part of carbon atoms are graphitized, and the I D /I G ratios are 1.09, 1.00, and 0.99. In CMs-N/P-n, N heteroatoms are dominated by pyridinic and pyrrodic N forms and P species dispersed in the skeleton as P  C, P  O, and PO species. In 6 M KOH, the optimized CMs-N/P-850 demonstrates a conspicuous specific...

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