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Study on the non-catalyzed oscillating reaction of dark tea-KBrO3-H2SO4 system

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成果类型:
期刊论文
作者:
Long, Liang;Xia, Li;Fang, Fang;Liu, Zheng;Wang, Jiaoliang
通讯作者:
Wang, JL
作者机构:
[Fang, Fang; Wang, Jiaoliang; Long, Liang; Wang, JL; Xia, Li; Liu, Zheng] Hunan City Univ, Coll Mat & Chem Engn, Yiyang 413000, Hunan, Peoples R China.
通讯机构:
[Wang, JL ] H
Hunan City Univ, Coll Mat & Chem Engn, Yiyang 413000, Hunan, Peoples R China.
语种:
英文
关键词:
Chemical oscillating reactions;Dark tea;Uncatalyzed bromate oscillator;OKN mechanism
期刊:
Reaction Kinetics, Mechanisms and Catalysis
ISSN:
1878-5190
年:
2024
页码:
1-12
基金类别:
Natural Science Foundation of Hunan Province [2021JJ30073]; NSFC [52102243]
机构署名:
本校为第一且通讯机构
摘要:
A new kinetic study of the uncatalyzed bromate oscillator using dark tea without pre-treatment was carried out. The difference of dark tea oscillating system with and without manganese ion as catalyst was compared. The reaction was studied with different starting concentrations of the reagents (sulfuric acid and potassium bromate) and the substrate of dark tea, and the results indicate that the concentration of dark tea has a wide range between 1 with 30 g/L in dark tea-KBrO3-H2SO4 system, the lowest concentration of potassium bromate and sulfuric acid are 0.028 mol/L and 0.24 mol/L. The effec...

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