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Synthesis of sulfonated naphthols via metal-free oxidative coupling of beta-tetralones and sodium sulfinates

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成果类型:
期刊论文
作者:
Liu, Saiwen;Xiao, Hong;Zhang, Jin;Yin, Zhihong
通讯作者:
Liu, SW
作者机构:
[Liu, Saiwen; Yin, Zhihong; Zhang, Jin; Liu, SW] Hunan City Univ, Coll Mat & Chem Engn, Yiyang 413000, Peoples R China.
[Liu, Saiwen; Xiao, Hong] Xiangtan Univ, Coll Chem, Xiangtan 411105, Peoples R China.
通讯机构:
[Liu, SW ] H
Hunan City Univ, Coll Mat & Chem Engn, Yiyang 413000, Peoples R China.
语种:
英文
关键词:
Sulfonylation;Dehydroaromatization;Naphthols;(3-tetralones;Sodium sulfinates;Metal-free
期刊:
Tetrahedron Letters
ISSN:
0040-4039
年:
2024
卷:
148
页码:
155209
基金类别:
Natural Science Foundation of Hunan Province [2022JJ50268]; Scientific Research Projects of Hunan Education Department [22B0779]
机构署名:
本校为第一且通讯机构
院系归属:
材料与化学工程学院
摘要:
The efficient synthesis of sulfonated naphthols was realized by dehydroaromatization of (3-tetralones with sodium sulfinates under metal-free conditions. Iodine-containing reagents played an important role in this oxidative coupling process. Sodium sulfinates served as a stable and readily available sulfur source, providing sulfones in good to excellent yields. A wide range of funct...

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