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La3+ and Al3+ loaded D151 as salt-resistant resins for efficient adsorption of glyphosate: Effects of ionic radius

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成果类型:
期刊论文
作者:
Xie, Huixian;Xiao, Guqing;Song, Qingwen;Meng, Qiudong
通讯作者:
Xiao, GQ
作者机构:
[Xiao, Guqing; Meng, Qiudong; Xie, Huixian; Song, Qingwen] Hunan City Univ, Coll Mat & Chem Engn, Yiyang 413000, Peoples R China.
通讯机构:
[Xiao, GQ ] H
Hunan City Univ, Coll Mat & Chem Engn, Yiyang 413000, Peoples R China.
语种:
英文
关键词:
Herbicides;Resins;Sodium chloride;Adsorption capacities;Adsorption mechanism;As-ligands;Glyphosates;High salts;Ionic radius;Ionization equilibrium;La 3+;Phosphonate group;Salt tolerance;Adsorption
期刊:
Journal of Applied Polymer Science
ISSN:
0021-8995
年:
2024
卷:
141
期:
1
页码:
e54756-
基金类别:
We acknowledge the support provided by National Natural Science Foundation of China (Grant No. 51678225), Nature Science Foundation of Hunan Province (Grant No. 2022JJ50278).
机构署名:
本校为第一且通讯机构
院系归属:
材料与化学工程学院
摘要:
La3+ and Al3+ loaded D151 resin [R-La and R-Al, respectively] were used as salt-resistant resins for the efficient adsorption of glyphosate. The results showed that La3+ with a larger ionic radius could accommodate more glyphosate as ligands, resulting in higher glyphosate adsorption capacity of R-La than that of R-Al. Both R-La and R-Al exhibited maximum adsorption capacities at pH 2.52, where glyphosate existed in its ionization equilibrium of pKa2. Consistent with the larger ionic radius of La3+, R-La featured larger qm and KL than R-Al at t...

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