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A novel chemometric coupling technique combined with HPLC-DAD for rapid quantification and source apportionment of monoaromatic hydrocarbons in soil samples

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成果类型:
期刊论文
作者:
Zhang, Zhen;Wang, You;Li, Xueqi;Wu, Xinran;Hu, Yunyi;...
通讯作者:
Xu, Ling;Qing, XD
作者机构:
[Qing, Xiangdong; Hu, Yunyi; Li, Xueqi; Zhang, Zhen; Wang, You; Wu, Xinran; Xu, Ling; An, Rong] Hunan City Univ, Coll Mat & Chem Engn, Hunan Prov Key Lab Dark Tea & Jin hua, Yiyang 413000, Peoples R China.
通讯机构:
[Qing, XD ; Xu, L] H
Hunan City Univ, Coll Mat & Chem Engn, Hunan Prov Key Lab Dark Tea & Jin hua, Yiyang 413000, Peoples R China.
语种:
英文
关键词:
Three-dimensional calibration;HPLC-DAD;MACHs;ATLD;t-SNE;PCA
期刊:
Microchemical Journal
ISSN:
0026-265X
年:
2025
卷:
210
页码:
112881
基金类别:
National Natural Science Foundation of China [21707032]; Research Foun-dation of Education Bureau of Hunan Province, China [21B0720]
机构署名:
本校为第一且通讯机构
院系归属:
材料与化学工程学院
摘要:
In the contribution, a novel chemometric coupling technique combined with high-performance liquid chromatography with diode array detector (HPLC-DAD) was developed for the rapid quantification and source apportionment of eight monoaromatic hydrocarbons (MACHs) in soil samples. The strategy was built on the three-dimensional calibration based on alternating trilinear decomposition coupling with the unsupervised classification using t-distributed stochastic neighbor embedding (named ATLD-t-SNE). Firstly, a validation set and a spiked soil set wer...

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