A novel chemometric coupling technique combined with HPLC-DAD for rapid quantification and source apportionment of monoaromatic hydrocarbons in soil samples
National Natural Science Foundation of China [21707032]; Research Foun-dation of Education Bureau of Hunan Province, China [21B0720]
机构署名:
本校为第一且通讯机构
院系归属:
材料与化学工程学院
摘要:
In the contribution, a novel chemometric coupling technique combined with high-performance liquid chromatography with diode array detector (HPLC-DAD) was developed for the rapid quantification and source apportionment of eight monoaromatic hydrocarbons (MACHs) in soil samples. The strategy was built on the three-dimensional calibration based on alternating trilinear decomposition coupling with the unsupervised classification using t-distributed stochastic neighbor embedding (named ATLD-t-SNE). Firstly, a validation set and a spiked soil set wer...