Enantiomerically Pure Chiral {CuII32}-Based 2D-Layered Frameworks: From the Asymmetric Octacopper(II) Subcomponents to 3D Hierarchical Supramolecular Structures

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成果类型：

期刊论文

作者：

Meng, Wei;Xu, Feng*;Xu, Weijian*

通讯作者：

Xu, Feng;Xu, Weijian

作者机构：

[Xu, Weijian; Xu, Feng; Meng, Wei; Xu, F; Xu, WJ] Hunan Univ, Coll Chem & Chem Engn, State Key Lab Chemo Biosensing & Chemometr, Changsha 410082, Hunan, Peoples R China.

[Meng, Wei] Hunan City Univ, Dept Chem & Environm Engn, Yiyang 413000, Peoples R China.

通讯机构：

[Xu, F; Xu, WJ] H

Hunan Univ, Coll Chem & Chem Engn, State Key Lab Chemo Biosensing & Chemometr, Changsha 410082, Hunan, Peoples R China.

语种：

英文

期刊：

INORGANIC CHEMISTRY

ISSN：

0020-1669

年：

2016

卷：

期：

页码：

2673-2675

DOI：

10.1021/acs.inorgchem.5b02654

基金类别：

National Natural Science Foundation of ChinaNational Natural Science Foundation of China (NSFC) [21301057]; Natural Science Foundation of Hunan ProvinceNatural Science Foundation of Hunan Province [14JJ3068]; Fundamental Research Funds for Central UniversitiesFundamental Research Funds for the Central Universities

机构署名：

本校为其他机构

院系归属：

材料与化学工程学院

摘要：

Two new chiral copper(II) coordination polymers comprising octacopper(II) subcomponents were synthesized through investigation of the interplay among tartrate ligands, guanidinium cations, and metals. Our analysis confirms that these compounds are enantiomers exhibiting 3D hierarchical supramolecular structures that are constituted by 2D sublayers and sustained by noncovalent bondin...

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Enantiomerically Pure Chiral {CuII32}-Based 2D-Layered Frameworks: From the Asymmetric Octacopper(II) Subcomponents to 3D Hierarchical Supramolecular Structures

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