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Application of alternating trilinear decomposition-assisted multivariate curve resolution to gas chromatography-mass spectrometric data for the quantification of polycyclic aromatic hydrocarbons in aerosols

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成果类型:
期刊论文
作者:
Qing, Xiangdong;Zhou, Xiaohong;Xu, Ling;Zhang, Jin;Huang, Yi;...
通讯作者:
Ling Xu<&wdkj&>Xiaohua Zhang<&wdkj&>Ling Xu<&wdkj&>Xiaohua Zhang
作者机构:
[Zhou, Xiaohong; Zhang, Jin; Li Lin; Xu, Ling; Huang, Yi; Qing, Xiangdong] Hunan City Univ, Coll Mat & Chem Engn, Hunan Prov Key Lab Dark Tea & Jin Hua, Yiyang 413000, Peoples R China.
[Liu, Zhi] Hunan Univ Humanities Sci & Technol, Coll Agr & Biotechnol, Loudi 417000, Peoples R China.
[Zhang, Xiaohua] Xuchang Univ, Food & Bioengn Coll, Key Lab Biomarker Based Rapid Detect Technol Food, Xuchang 461000, Peoples R China.
语种:
英文
关键词:
PAHs;alternating trilinear decomposition-assisted multivariate curve resolution;multivariate curve resolution-alternating least-squares;GC-MS;aerosol
期刊:
ROYAL SOCIETY OPEN SCIENCE
ISSN:
2054-5703
年:
2021
卷:
8
期:
8
基金类别:
National Natural Science Foundation of ChinaNational Natural Science Foundation of China (NSFC) [21707032, 31701689]; China Scholarship CouncilChina Scholarship Council [202008430147]; Hunan Provincial Natural Science FoundationNatural Science Foundation of Hunan Province [2021JJ50151]; Research Foundation of Education Bureau of Hunan Province, China [16A109, 19C0345]
机构署名:
本校为第一机构
院系归属:
材料与化学工程学院
摘要:
For the first time, alternating trilinear decomposition-assisted multivariate curve resolution (ATLD-MCR) was applied to analyse complex gas chromatography-mass spectrometric (GC-MS) data with severe baseline drifts, serious co-elution peaks and slight retention time shifts for the simultaneous identification and quantification of polycyclic aromatic hydrocarbons (PAHs) in aerosols. It was also compared with the classic multivariate curve resolution-alternating least-squares (MCR-ALS) and the GC-MS-based external standard method. In validation samples, average recoveries of five PAHs were with...

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