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Determination of trace thallium by flow injection combined with graphite furnace atomic absorption spectrometer based on immobilized p-dimethylaminobenzylidenerhodanine separation and preconcentration

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成果类型:
期刊论文
作者:
Liu, Bangfu;He, Guo-wen;Zhou, Le-zhou
通讯作者:
Zhou, LZ
作者机构:
[Liu, Bangfu] Hunan Elect Informat Ind Inst, Changsha, Peoples R China.
[He, Guo-wen] Hunan City Univ, Coll Mat & Chem Engn, Yiyang, Peoples R China.
[Zhou, Le-zhou] Hunan Prevent & Treatment Inst Occupat Dis, Changsha, Peoples R China.
[Zhou, Le-zhou; Zhou, LZ] Hunan Prevent & Treatment Inst Occupat Dis, Changsha 410007, Hunan, Peoples R China.
通讯机构:
[Zhou, LZ ] H
Hunan Prevent & Treatment Inst Occupat Dis, Changsha 410007, Hunan, Peoples R China.
语种:
英文
关键词:
Furnace atomic absorption spectrometer;immobilized p-dimethylaminobenzylidenerhodanine;separation and preconcentration;TiO2 nanoparticles;trace thallium
期刊:
Journal of Chemical Research
ISSN:
1747-5198
年:
2024
卷:
48
期:
1
基金类别:
The author(s) disclosed receipt of the following financial support for the research, authorship, and/or publication of this article: This work was supported by Hunan Provincial National Health Commission of China (No. 202212065516).
机构署名:
本校为其他机构
院系归属:
材料与化学工程学院
摘要:
The novelty of immobilized p-dimethylaminobenzylidenerhodanine is successfully prepared by using TiO2-based nanoparticles as the carrier. It is applied to preconcentrate and separate trace thallium and detect by flow injection combined with graphite furnace atomic absorption spectrometer. The results show that immobilized p-dimethylaminobenzylidenerhodanine can preconcentrate and separate trace thallium and eliminate the interference of many other ions. The optimal adsorption occurs at pH = 3.5, the retention time is 2.0 min, and the flow veloc...

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