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采用气相色谱-质谱法分析药对麻黄-羌活的挥发油

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成果类型:
期刊论文
作者:
李国辉;李晓如;邹桥;谭斌斌
通讯作者:
Li, G.-H.
作者机构:
[李晓如; 邹桥; 谭斌斌; 李国辉] School of Chemistry and Chemical Engineering, Central South University, Changsha 410083, China
[李国辉] Department of Chemistry and Environment Engineering, Hunan City College, Yiyang 413000, China
通讯机构:
School of Chemistry and Chemical Engineering, Central South University, China
语种:
中文
关键词:
药对麻黄-羌活;挥发油;气相色谱-质谱;化学计量学解析法
关键词(英文):
Chemometric resolution method;Drug pair Herba Ephedrae-Rhizoma seu Radix Notopeterygii;Essential oil;Gas chromatography-mass spectrometry
期刊:
中南大学学报(自然科学版)
ISSN:
1672-7207
年:
2007
卷:
38
期:
5
页码:
888-892
基金类别:
国家自然科学基金资助项目(20235020);
机构署名:
本校为其他机构
院系归属:
材料与化学工程学院
摘要:
采用气相色谱-质谱(GC-MS)法分离测定了药对麻黄-羌活、单味药麻黄和羌活的挥发油,并对其重叠色谱峰采用化学计量学解析法进行了分辨,得到药对和各单味药的纯色谱曲线和质谱.药对麻黄-羌活、单味药麻黄和羌活分辨出的色谱峰,通过质谱库对其进行定性,分别得到58,51和52个定性结果,占总含量的83.75%,88.70%和80.79%.实验结果表明:药对麻黄-羌活中挥发油化学成分有40种来自羌活,13种来自麻黄,新产生了10种化合物.
摘要(英文):
Determination of volatile components in drug pair (DP) Herba Ephedrae-Rhizoma seu Radix Notopeterygii (HE-RsRN), single drug HE and RsRN was performed using two-dimensional gas chromatography-mass spectrometry (GC-MS) data coupled with chemometric resolution method (CRM). With the help of CRM, the two-dimensional data obtained from GC-MS instruments were resolved into a pure chromatogram and a mass spectrum of each chemical compound. Using these methods to process two-dimensional data, 51, 52, and 58 volatile chemical components in essential oil of HE, RsRN, and DP HE-RsRN were respectively de...

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