期刊论文

中文

合成化学

1005-1511

2001

9

5

457-458+472

10.3969/j.issn.1005-1511.2001.05.019

湖南省自然科学基金资助课题 （ 0 0JJY2 0 110 ）； 湖南省教育厅科研资助课题 （ 0 0C0 15 ）；

本校为第一机构

硫酸氢钠能够代替硫酸作为酯化催化剂.利用一水硫酸氢钠催化合成了甲酸烯丙酯、乙酸烯丙酯,丙酸烯丙酯、丁酸烯丙酯和戊酸烯丙酯,产物用折射率、元素分析和红外光谱表征.研究了硫酸氢钠用量对丙酸烯丙酯收率的影响.

Sodium bisulfate can be used as catalyst for the esterification instead of sulfuric acid. The effect of the amount of sodium bisulfate on the yield of allyl propionate have been invostigated. Catalytic synthesis of allyl formate, allyl acetate, allyl propionate, allyl butyrate and allyl valerate with sodium bisulfate monohydrate was reproted, All the products were characteriz...