1 INTRODUCTION
Catalytic hydrodechlorination is an elegant reaction for disposal of environmentally hazardous chlorocarbons,such as chloro-benzene[1].Development of a new catalyst with excellent stability is necessary due to the deactivation of supported noble metal catalysts[1].However the modification of catalytic properties of catalysts in hydrodechlorination reaction by introducing stable ligands to noble metals has been the least studied.Here the synthesis of Pd(Ⅱ) 2,9,16,23-symetrically tetrasubstituted phthalocyanines PdPTX4 (where X=-...