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Synthesis of symmetrically tetra-substituted palladium phthalocyanines as catalysis for hydrodechlorination of chlorobenzene in gas phase

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成果类型:
期刊论文
作者:
丁亮中;钟桐生
作者机构:
[丁亮中; 钟桐生] Department of Chemistry, Hunan City College
语种:
中文
关键词:
PALLADIUM;PHTHALOCYANINE;CHLOROBENZENE;CATALYTIC;HYDRODECHLORINATION;palladium phthalocyanine;chlorobenzene;catalytic hydrodechlorination
期刊:
化工学报
ISSN:
0438-1157
年:
2002
卷:
53
期:
5
页码:
450-451
基金类别:
supportedbytheProvincialNaturalScienceFoundationofHunan(No.0 0JJY2 0 110 );
机构署名:
本校为其他机构
院系归属:
材料与化学工程学院
摘要:
1 INTRODUCTION Catalytic hydrodechlorination is an elegant reaction for disposal of environmentally hazardous chlorocarbons,such as chloro-benzene[1].Development of a new catalyst with excellent stability is necessary due to the deactivation of supported noble metal catalysts[1].However the modification of catalytic properties of catalysts in hydrodechlorination reaction by introducing stable ligands to noble metals has been the least studied.Here the synthesis of Pd(Ⅱ) 2,9,16,23-symetrically tetrasubstituted phthalocyanines PdPTX4 (where X=-...

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