For the comprehensive utilization of antimony smelting arsenic-alkali residue, there are some problems such as the incomplete separation and low recoveries of arsenic and alkali, and the formation of arsenic-alkali mixed salts with secondary pollution. In order to solve these problems, the leaching solution of arsenic-alkali residue (arsenic-alkali solution) was used as a raw material in this study, and a novel process of twice alkali recovery with CO2, deep alkali removal with H2SO4, As(V) reduction with SO2 and evaporation concentration to re...