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Electrically driven single-atom Mo enhances support effect for efficient PMS activation to degrade high-concentration sulfanilamide

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成果类型:
期刊论文
作者:
Li, Yun;Yang, Yanjing;Gong, Zan;Xiao, Liuyue;Chen, Siyi;...
通讯作者:
Zhong, S;He, GW
作者机构:
[Chen, Siyi; Li, Yun; Chen, Ping; Zhong, Shian; Tang, Yalan; Gong, Zan; Xiao, Liuyue; Yang, Yanjing] Cent South Univ, Coll Chem & Chem Engn, Changsha 410083, Peoples R China.
[He, Guowen] Hunan City Univ, Coll Mat & Chem Engn, Coll Hunan Prov, Key Lab low carbon & Environm funct Mat, Yiyang 413000, Peoples R China.
[Zhong, Shian] Changsha Med Univ, Hunan Prov Key Lab Res & Dev Novel Pharmaceut Prep, Double Class Applicat Characterist Discipline Huna, Changsha 410219, Peoples R China.
通讯机构:
[Zhong, S ] C
[He, GW ] H
Cent South Univ, Coll Chem & Chem Engn, Changsha 410083, Peoples R China.
Hunan City Univ, Coll Mat & Chem Engn, Coll Hunan Prov, Key Lab low carbon & Environm funct Mat, Yiyang 413000, Peoples R China.
Changsha Med Univ, Hunan Prov Key Lab Res & Dev Novel Pharmaceut Prep, Double Class Applicat Characterist Discipline Huna, Changsha 410219, Peoples R China.
语种:
英文
关键词:
Single atom catalysts;3D electrocatalytic system;Singlet oxygen;Sulfanilamide;Peroxymonosulfate
期刊:
Chemical Engineering Journal
ISSN:
1385-8947
年:
2025
卷:
521
页码:
166845
基金类别:
National Natural Science Foundation of China [22278445]
机构署名:
本校为通讯机构
院系归属:
材料与化学工程学院
摘要:
Sulfanilamide (SN), characterized by its structural stability and resistance in natural degradation, has emerged as a persistent organic pollutant of great concern in aquatic environments. To address the challenge of efficiently removing high concentrations of SN, this study developed a three-dimensional catalytic degradation system (Mo SACs -CoCO 3 /3D-EC/PMS). In this system, single-atom molybdenum (Mo) not only serves as a highly active catalytic center but also enhances the synergistic effect of the support through electronic modulation. Under the influence of an external electric field, t...

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